Sorption and Separation of Optical Isomers of 2-Butanol by Chiral Porous Coordination Polymers View Full Text


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Article Info

DATE

2015-03

AUTHORS

Yu. A. Satska, N. P. Komarova, K. S. Gavrilenko, O. V. Manoylenko, Zh. V. Chernenko, M. A. Kiskin, S. V. Kolotilov, I. L. Eremenko, V. M. Novotortsev

ABSTRACT

It was shown that porous coordination polymers (PCPs) of 3d metals containing chiral centers in fragments of deprotonated (S)-lactic and (R)-aspartic acid or trimesoyl-(S)-alanine are characterized by different values of sorption capacity with respect to the individual optical isomers of 2-butanol upon sorption of such substrates from the gas phase. The difference between the sorption capacity values with respect to the (R) and (S) isomers of 2-butanol correlates with the value of the enantiomeric excess achieved upon separation of the alcohol racemate on the respective PCP by column chromatography. More... »

PAGES

45-53

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11237-015-9396-8

DOI

http://dx.doi.org/10.1007/s11237-015-9396-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017563968


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