Exchange Interactions in Cobalt(II) and Nickel(II) Complexes Containing M4(μ3-OH)2 Metal Cores with Distorted Rhombic Topology View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-01

AUTHORS

A. E. Goldberg, G. G. Aleksandrov, A. S. Bogomyakov, M. A. Kiskin, S. V. Kolotilov, I. A. Utepova, A. A. Sidorov, O. N. Chupakhin, I. L. Eremenko

ABSTRACT

Antiferromagnetic interactions between the Co2+ or Ni2+ ions were found in complexes [(μ3 ‐ L)2Co5II(μ ‐ OH)2(Piv)7(NO3)] and [(μ3 ‐ L)2(HPiv)Ni4II(μ3 ‐ OH)2(Piv)4(NO3)2] (Piv– = pivalic acid anion, L = 1,1′-dipyridazinylferrocene) possessing a metal core with distorted rhombic topology M4(μ3-OH)2. In contrast to the case of symmetrical analogs, the signs of all the exchange interaction parameters J were determined unambiguously. More... »

PAGES

364-370

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11237-015-9389-7

DOI

http://dx.doi.org/10.1007/s11237-015-9389-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043293230


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