New carbacylamidophosphates (CAPh) and CAPh-containing coordination compounds: structural peculiarities View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-02

AUTHORS

Olena O. Litsis, Iuliia O. Shatrava, Oleksiy V. Amirkhanov, Vladimir A. Ovchynnikov, Tatiana Yu. Sliva, Svetlana V. Shishkina, Viktoriya V. Dyakonenko, Oleg V. Shishkin, Vladimir M. Amirkhanov

ABSTRACT

The new carbacylamidophosphate derivative HL1 (1) with general formula Cl3CC(O)N(H)P(O)(CH2C5H4N)2 named 2,2,2-trichloro-N-(3-(aminomethyl)pyridine)-1-yl-phosphoryl)-acetamide), the potassium, lanthanide and uranyl (VI) complexes with the different CAPh ligands: KL2·H2O (2) and Eu(L2)3·H2O (3) with 2,2,2-trichloro-N-(dimorpholinophosphoryl)acetamide (CCl3C(O)N(H)P(O)(N(C2H4)2O)2, HL2), Ce(L3)3(i-PrOH)2·i-PrOH (4) with N-(bis(phenylamino)phosphoryl)-2,2,2-trichloroacetamide (CCl3C(O)N(H)P(O)(NHC6H5)2, HL3), Nd(NO3)3(HL4)2 (5), Nd(NO3)3(HL5)2 (6) and UO2(NO3)2(HL5)2 (7) (HL4=CH3(C4H3N)C(O)N(H)P(O)(N(CH3)2)2 –N-(bis(dimethylamino)phosphoryl)-1-methyl-1H-pyrrole-2-carboxamide, HL5=CH3(C4H3N)C(O)N(H)P(O)(N(C2H5)2)2—N-(bis(diethylamino)phosphoryl)-1-methyl-1H-pyrrole-2-carboxamide) have been synthesized. Obtained compounds were characterized by means of FTIR, 1H and 31P NMR spectroscopy. Crystal structures of 1–7 have been determined. Compound 2 represents the first structure of the deprotonated CAPh compounds with bridging function of both carbonyl and phosphoryl groups. Structural peculiarities of CAPh ligands in the composition of the synthesized coordination compounds are discussed. More... »

PAGES

341-355

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11224-015-0701-x

DOI

http://dx.doi.org/10.1007/s11224-015-0701-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028450911


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    "description": "The new carbacylamidophosphate derivative HL1 (1) with general formula Cl3CC(O)N(H)P(O)(CH2C5H4N)2 named 2,2,2-trichloro-N-(3-(aminomethyl)pyridine)-1-yl-phosphoryl)-acetamide), the potassium, lanthanide and uranyl (VI) complexes with the different CAPh ligands: KL2\u00b7H2O (2) and Eu(L2)3\u00b7H2O (3) with 2,2,2-trichloro-N-(dimorpholinophosphoryl)acetamide (CCl3C(O)N(H)P(O)(N(C2H4)2O)2, HL2), Ce(L3)3(i-PrOH)2\u00b7i-PrOH (4) with N-(bis(phenylamino)phosphoryl)-2,2,2-trichloroacetamide (CCl3C(O)N(H)P(O)(NHC6H5)2, HL3), Nd(NO3)3(HL4)2 (5), Nd(NO3)3(HL5)2 (6) and UO2(NO3)2(HL5)2 (7) (HL4=CH3(C4H3N)C(O)N(H)P(O)(N(CH3)2)2 \u2013N-(bis(dimethylamino)phosphoryl)-1-methyl-1H-pyrrole-2-carboxamide, HL5=CH3(C4H3N)C(O)N(H)P(O)(N(C2H5)2)2\u2014N-(bis(diethylamino)phosphoryl)-1-methyl-1H-pyrrole-2-carboxamide) have been synthesized. Obtained compounds were characterized by means of FTIR, 1H and 31P NMR spectroscopy. Crystal structures of 1\u20137 have been determined. Compound 2 represents the first structure of the deprotonated CAPh compounds with bridging function of both carbonyl and phosphoryl groups. Structural peculiarities of CAPh ligands in the composition of the synthesized coordination compounds are discussed.", 
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RDF/XML is a standard XML format for linked data.

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