Synthesis of New Derivatives of Protoporphyrin IX and Chlorophyll a View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-12

AUTHORS

V. Yu. Pavlov, I. O. Konstantinov, G. V. Ponomarev, V. P. Timofeev, B. G. Kimel'

ABSTRACT

The vinyl groups in protoporphyrin IX and chlorophyll a derivatives were selectively transformed into hydroxymethyl and acetoxymethyl substituents. The reactivities of β-hydroxymethyl and β-acetoxymethyl groups in porphyrins and chlorins toward nucleophilic reagents were compared for the first time using the reaction with acetylacetone as an example. Peripheral acetylacetone moieties in porphyrins and chlorins were shown to be promising as building blocks for generation of exo heterocyclic structures. More... »

PAGES

1824-1835

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11178-006-0044-6

DOI

http://dx.doi.org/10.1007/s11178-006-0044-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012748737


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