Molecular Structure of Complexes with Bifurcated Hydrogen Bond: III. Solvate H-Complexes Formed by Trifluoromethanesulfonamide and Its Cyclic Dimer View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-10

AUTHORS

N. N. Chipanina, T. N. Aksamentova, L. V. Sherstyannikova, I. V. Sterkhova, B. A. Shainyan, V. K. Turchaninov

ABSTRACT

According to the data of IR spectroscopy, dielcometry, and B3LYP/6-31G* quantum-chemical calculations, trifluoromethanesulfonamide homoassociates in weakly basic protophilic media are converted into 2 : 1 solvate H-complexes. Cyclic trifluoromethanesulfonamide dimer decomposes in heteroassociate with dioxane with a composition of 1 : 3. Cyclic trifluoromethanesulfonamide dimer with dioxane forms a 1 : 4 H-complex with bifurcated (three-center) hydrogen bond involving the bridging hydrogen atom of the NH group (NH⋯O). More... »

PAGES

1415-1420

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11178-005-0360-2

DOI

http://dx.doi.org/10.1007/s11178-005-0360-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015660380


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