Reactivity of 3,5-bis-(4-amino-1,2,5-oxadiazol-3-yl)-1,2,4-triazole View Full Text


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Article Info

DATE

2005-02

AUTHORS

A. V. Sergievskii, T. V. Romanova, S. F. Mel’nikova, I. V. Tselinskii

ABSTRACT

Alkylation of 3,5-bis(4-amino-1,2,5-oxadiazol-3-yl)-1,2,4-triazole with haloalkanes afforded N-CH2R derivatives, and nitration furnished the corresponding bis-N-nitramine isolated as a trisodium salt. Treatment of the latter with CH3I resulted in denitration. Diazotization and oxidation of 3,5-bis(4-amino-1,2,5-oxadiazol-3-yl)-1,2,4- triazole, its N-methyl and N-carboxy derivatives gave rise to the corresponding azido and nitro derivatives. Salts of 3,5-bis(4-amino-1,2,5-oxadiazol-3-yl)-1,2,4-triazol-5-acetic acid with nitrogen-containing bases were synthesized. It was established that the character of reaction products of 3,5-bis(4-amino-1,2,5-oxadiazol-3-yl)-1,2,4-triazole with formaldehyde depended on the acid-base properties of the medium. More... »

PAGES

261-267

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11178-005-0154-6

DOI

http://dx.doi.org/10.1007/s11178-005-0154-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035557903


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