1,3-dipolar cycloaddition of trimethylsilyl azide to propynals and dimerization of 1H-1,2,3-triazole-5-carbaldehydes to tricyclic bis-hemiaminals View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-12

AUTHORS

M. M. Demina, P. S. Novopashin, G. I. Sarapulova, L. I. Larina, A. S. Smolin, V. S. Fundamenskii, A. A. Kashaev, A. S. Medvedeva

ABSTRACT

Reactions of trimethylsilyl azide with 3-trimethylsilyl-2-propynal and 2-propynal were studied. X-Ray analysis of the molecular structure of 4-trimethylsilyl-1H-1,2,3-triazole-5-carbaldehyde showed that the carbonyl group appears in the s-cis conformation with respect to the double C=C bond in the heteroring. The effect of the temperature and polarity of the medium on the ability of 1H-1,2,3-triazole-5-carbaldehyde to undergo dimerization to tricyclic bis-hemiaminals was examined by IR and 1H NMR spectroscopy. More... »

PAGES

1804-1809

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11178-005-0103-4

DOI

http://dx.doi.org/10.1007/s11178-005-0103-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023754765


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