Self-Association of Trifluoromethanesulfonamide in Inert Solvents View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-06

AUTHORS

N. N. Chipanina, L. V. Sherstyannikova, I. V. Sterkhova, T. N. Aksamentova, V. K. Turchaninov, B. A. Shainyan

ABSTRACT

Trifluoromethanesulfonamide exists in inert solvents as an equilibrium mixture of the monomer and self-associates of the structure depending on the solvent polarity. In low-polarity CCl4 and C2Cl4, a cyclic tetramer is formed, in which the NH2 group is involved in two NH⋯O=S hydrogen bonds; in moderately polar CHCl3, the compound forms cyclic trimers in which one of the hydrogen atoms of the NH2 group is not involved in hydrogen bonding; in highly polar C2HCl5 and C2H4Cl2, the compound forms chain-like dimers. More... »

PAGES

876-882

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11176-005-0339-2

DOI

http://dx.doi.org/10.1007/s11176-005-0339-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030056976


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