Cyclocondensations of Amidophenacylation Products of Triphenylphosphoranylideneacetonitrile View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-04

AUTHORS

S. Ya. Panchishin, O. B. Smolii, A. N. Chernega, E. B. Rusanov, B. S. Drach

ABSTRACT

When heated in polyphosphoric acid, the products of amidophenacylation of the available triphenylphosphoranylideneacetonitrile undergo the Robinson-Gabriel cyclization followed by other transformations. Treatment of the resulting mixture with sodium perchlorate gave quaternary phosphonium salts of two types, viz. (2, 5-diaryl-1, 3-oxazol-4-ylmethyl) triphenylphosphonium perchlorates and [2-aryl-5-hydroxynaphtho[2, 1-d][1,3]oxazol-4-yl]triphenylphosphonium perchlorates. The first of these products was identified by alkaline dephosphorylation, and the structure of one of the representatives of the second class of compounds was established by X-ray diffraction. More... »

PAGES

518-522

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11176-005-0264-4

DOI

http://dx.doi.org/10.1007/s11176-005-0264-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023491812


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