Influence of the Structure of the Organic Moiety of Copper(II) Porphyrins on Their Reactivity toward Acids View Full Text


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Article Info

DATE

2005-03

AUTHORS

O. V. Kosareva, M. E. Klyueva, T. N. Lomova, E. E. Suslova

ABSTRACT

The acid-induced dissociation of copper(II) porphyrin complexes with a high degree of meso- and β-substitution in the ligand was studied. The copper(II) complexes with octaethylporphyrins containing 0, 1, 2, 3, and 4 meso-phenyl substituents were ranked with respect to the stability. Octaβ-alkyl and unsymmetrical meso-phenyl substitution affects not only the quantitative characteristics of dissociation of the complexes but also the kinetic relationships of the process. More... »

PAGES

461-467

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11176-005-0250-x

DOI

http://dx.doi.org/10.1007/s11176-005-0250-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037304992


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