Competitive Coordination of 2-[(Diorganylphosphinoyl)-hydroxymethyl)]-1-organylimidazoles with Metal Chlorides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-02

AUTHORS

L. V. Baikalova, I. A. Zyryanova, N. N. Chipanina, L. M. Sinegovskaya, N. I. Ivanova, T. V. Mamaseva, N. K. Gusarova, A. V. Afonin, B. V. Trofimov

ABSTRACT

The structure of complexes of bivalent cobalt, copper, zinc, cadmium, and palladium chloride and tetravalent tin chlorides with 1-organyl-2- [(diorganylphosphinoyl)hydroxymethyl]imidazoles, synthesized for the first time, was studied by 1H NMR and IR spectroscopy. The formation of two types of metal complexes, molecular (Zn, Cd, Pd, Sn) and chelate (Co, Cu), was established. For crystalline 1 : 1 complexes, the structures with imidazolylphosphine oxide playing the role of an N3,O-bidentate ligand were proposed. In 2L : 1 complexes, these ligands are monodentate and coordinate by the P=O oxygen atom. In DMSO solutions, the molecular complexes undergo dissociation to form coordination compounds in which, depending of the nature of the ligand, either M←N3 or M←O donor-acceptor bond takes place. More... »

PAGES

200-206

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11176-005-0198-x

DOI

http://dx.doi.org/10.1007/s11176-005-0198-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012341061


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