Reactions of N-aroxycarbonyltrichloroacetimidates with nucleophilic phosphorus derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-11

AUTHORS

Yu. V. Rassukanaya, P. P. Onys’ko, A. D. Sinitsa, A. V. Bol’but, A. N. Chernega

ABSTRACT

Aryl N-aroxycarbonyltrichloroacetimidates (Ar = Ph, 4-FC6H4) react with diphenylphosphinite according to the scheme of the aza-Perkow reaction to give the corresponding aryl N-(1-aroxy-2,2-dichloro-vinyl)-N-diphenylphosphinoylcarbamates. The structure of one of these compounds was confirmed by single crystal X-ray diffraction analysis. In the case of electron-accepting substituents (Ar = 4-O2N6H4), the primary product undergoes mild β-elimination to give nitrophenyl diphenylphosphinate and 1-nitrophenoxy-2,2-dichlorovinyl isocyanate. The reaction of trichloroacetimidates with triethyl phosphite yields a mixture of O- and N-phosphorylation products. More... »

PAGES

1673-1678

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11176-005-0082-8

DOI

http://dx.doi.org/10.1007/s11176-005-0082-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012368979


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