Self-association of N-methyltrifluoromethanesulfonamide in the gas phase and in inert solvents View Full Text


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Article Info

DATE

2004-10

AUTHORS

N. N. Chipanina, L. V. Sherstyannikova, V. K. Turchaninov, B. A. Shainyan

ABSTRACT

IR spectroscopy and quantum-chemical calculations (B3LYP/6-31G*) were used to show that N-methyltrifluoromethanesulfonamide in the gas phase and in a low-polarity inert solvent (CCl4) exists as an equilibrium mixture of monomers and cyclic dimers. In a more polar solvent (CH2Cl2), highly polar open-chain dimers are stabilized.

PAGES

1538-1542

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11176-005-0051-2

DOI

http://dx.doi.org/10.1007/s11176-005-0051-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048522134


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