Crystal Structure of Neptunium(V) Acetate [(NpO2)2(OOCCH3)2(H2O)] ⋅ 2H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-11

AUTHORS

G. B. Andreev, M. Yu. Antipin, N. A. Budantseva, N. N. Krot

ABSTRACT

A new neptunium(V) complex [(NpO2)2(CH3COO)2(H2O)] ⋅ 2H2O was synthesized and its crystal structure was determined. The unit cell parameters are: a = 24.007(10) Å, b = 6.779(3) Å, c = 8.076(3) Å, space group Pnma, Z = 4, V = 1314.2(9) Å3, R = 0.049, wR(F2) = 0.105. The crystal structure of the compound is composed of neutral [(NpO2)2(CH3COO)2(H2O)] layers and molecules of the water of crystallization. Each of the crystallographically independent neptunoyl ions performs a bidentate function thus forming a composite system of cation-cation bonds. More... »

PAGES

800-803

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11173-005-0172-5

DOI

http://dx.doi.org/10.1007/s11173-005-0172-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033596076


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Andreev", 
        "givenName": "G. B.", 
        "id": "sg:person.01025137037.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01025137037.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antipin", 
        "givenName": "M. Yu.", 
        "id": "sg:person.010142146727.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010142146727.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Budantseva", 
        "givenName": "N. A.", 
        "id": "sg:person.01073252237.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01073252237.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Krot", 
        "givenName": "N. N.", 
        "id": "sg:person.01122006570.68", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01122006570.68"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1021/ic50173a010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055577024"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2005-11", 
    "datePublishedReg": "2005-11-01", 
    "description": "A new neptunium(V) complex [(NpO2)2(CH3COO)2(H2O)] \u22c5 2H2O was synthesized and its crystal structure was determined. The unit cell parameters are: a = 24.007(10) \u00c5, b = 6.779(3) \u00c5, c = 8.076(3) \u00c5, space group Pnma, Z = 4, V = 1314.2(9) \u00c53, R = 0.049, wR(F2) = 0.105. The crystal structure of the compound is composed of neutral [(NpO2)2(CH3COO)2(H2O)] layers and molecules of the water of crystallization. Each of the crystallographically independent neptunoyl ions performs a bidentate function thus forming a composite system of cation-cation bonds.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11173-005-0172-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "31"
      }
    ], 
    "name": "Crystal Structure of Neptunium(V) Acetate [(NpO2)2(OOCCH3)2(H2O)] \u22c5 2H2O", 
    "pagination": "800-803", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "a00a4d11f1243a43e2071a3108df130ce2def4f904c192b516dcd2c616fbd634"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11173-005-0172-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1033596076"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11173-005-0172-5", 
      "https://app.dimensions.ai/details/publication/pub.1033596076"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:21", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000362_0000000362/records_87082_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11173-005-0172-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11173-005-0172-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11173-005-0172-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11173-005-0172-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11173-005-0172-5'


 

This table displays all metadata directly associated to this object as RDF triples.

86 TRIPLES      21 PREDICATES      28 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11173-005-0172-5 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N4f0d572255c04b32abdc64f9e3864c6a
4 schema:citation https://doi.org/10.1021/ic50173a010
5 schema:datePublished 2005-11
6 schema:datePublishedReg 2005-11-01
7 schema:description A new neptunium(V) complex [(NpO2)2(CH3COO)2(H2O)] ⋅ 2H2O was synthesized and its crystal structure was determined. The unit cell parameters are: a = 24.007(10) Å, b = 6.779(3) Å, c = 8.076(3) Å, space group Pnma, Z = 4, V = 1314.2(9) Å3, R = 0.049, wR(F2) = 0.105. The crystal structure of the compound is composed of neutral [(NpO2)2(CH3COO)2(H2O)] layers and molecules of the water of crystallization. Each of the crystallographically independent neptunoyl ions performs a bidentate function thus forming a composite system of cation-cation bonds.
8 schema:genre research_article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N8c9d120ecdc9455da2534b9d923d5599
12 Neac71903748346309c844c8e1fc3986a
13 sg:journal.1294773
14 schema:name Crystal Structure of Neptunium(V) Acetate [(NpO2)2(OOCCH3)2(H2O)] ⋅ 2H2O
15 schema:pagination 800-803
16 schema:productId N615aa0a50e6c424daf9383c25b12b967
17 N67cb7226bae049579864f74514543c56
18 Nf3651c047e8944dcbd482709d2a9449c
19 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033596076
20 https://doi.org/10.1007/s11173-005-0172-5
21 schema:sdDatePublished 2019-04-11T12:21
22 schema:sdLicense https://scigraph.springernature.com/explorer/license/
23 schema:sdPublisher N66ac80b2231549aa84c753753240d1a2
24 schema:url http://link.springer.com/10.1007%2Fs11173-005-0172-5
25 sgo:license sg:explorer/license/
26 sgo:sdDataset articles
27 rdf:type schema:ScholarlyArticle
28 N21b8c5a2b3cd417696556b5f4726f904 rdf:first sg:person.01073252237.09
29 rdf:rest N2334455d37dd4811befda645856040c5
30 N2334455d37dd4811befda645856040c5 rdf:first sg:person.01122006570.68
31 rdf:rest rdf:nil
32 N4f0d572255c04b32abdc64f9e3864c6a rdf:first sg:person.01025137037.12
33 rdf:rest N658b9b2923914830b4f1c6c6134d4cef
34 N615aa0a50e6c424daf9383c25b12b967 schema:name doi
35 schema:value 10.1007/s11173-005-0172-5
36 rdf:type schema:PropertyValue
37 N658b9b2923914830b4f1c6c6134d4cef rdf:first sg:person.010142146727.55
38 rdf:rest N21b8c5a2b3cd417696556b5f4726f904
39 N66ac80b2231549aa84c753753240d1a2 schema:name Springer Nature - SN SciGraph project
40 rdf:type schema:Organization
41 N67cb7226bae049579864f74514543c56 schema:name dimensions_id
42 schema:value pub.1033596076
43 rdf:type schema:PropertyValue
44 N8c9d120ecdc9455da2534b9d923d5599 schema:volumeNumber 31
45 rdf:type schema:PublicationVolume
46 Neac71903748346309c844c8e1fc3986a schema:issueNumber 11
47 rdf:type schema:PublicationIssue
48 Nf3651c047e8944dcbd482709d2a9449c schema:name readcube_id
49 schema:value a00a4d11f1243a43e2071a3108df130ce2def4f904c192b516dcd2c616fbd634
50 rdf:type schema:PropertyValue
51 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
52 schema:name Chemical Sciences
53 rdf:type schema:DefinedTerm
54 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
55 schema:name Physical Chemistry (incl. Structural)
56 rdf:type schema:DefinedTerm
57 sg:journal.1294773 schema:issn 1070-3284
58 1608-3318
59 schema:name Russian Journal of Coordination Chemistry
60 rdf:type schema:Periodical
61 sg:person.010142146727.55 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
62 schema:familyName Antipin
63 schema:givenName M. Yu.
64 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010142146727.55
65 rdf:type schema:Person
66 sg:person.01025137037.12 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
67 schema:familyName Andreev
68 schema:givenName G. B.
69 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01025137037.12
70 rdf:type schema:Person
71 sg:person.01073252237.09 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
72 schema:familyName Budantseva
73 schema:givenName N. A.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01073252237.09
75 rdf:type schema:Person
76 sg:person.01122006570.68 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
77 schema:familyName Krot
78 schema:givenName N. N.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01122006570.68
80 rdf:type schema:Person
81 https://doi.org/10.1021/ic50173a010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055577024
82 rdf:type schema:CreativeWork
83 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
84 schema:name Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia
85 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
86 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...