Ontology type: schema:ScholarlyArticle
2005-11
AUTHORSV. O. Gel'mbol'dt, L. V. Koroeva, Ya. E. Filinchuk
ABSTRACTFluosilicic acid reacts with solutions of N,N-di-tert-butylurea (DTBU) in methanol or acetone to form crystalline compounds 2DTBU ⋅ H2SiF6 and 2DTBU ⋅ H2SiF6 ⋅ Me2CO, which were characterized by the IR and 19F NMR spectra and mass spectroscopy supplemented by theoretical calculations. According to the data of IR and 19F NMR spectra, the complexes are hexafluorosilicates of O-protonated DTBU. They undergo hydrolysis in organic media with water traces; their solubility in water is very low (0.10 and 0.14 wt %, respectively). In the DTBU structure, two independent ligand molecules are joined by hydrogen bonds NH⋯O(N⋯O) 2.888(5)–2.944(5) Å). More... »
PAGES775-779
http://scigraph.springernature.com/pub.10.1007/s11173-005-0168-1
DOIhttp://dx.doi.org/10.1007/s11173-005-0168-1
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