Some properties of rhodium thioselenochloride RhCl4Se6S9 and its thermal conversion products View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-12

AUTHORS

V. I. Pekhno, I. N. Stepanenko, S. V. Volkov, Z. A. Fokina, A. M. Korduban

ABSTRACT

The structure of rhodium thioselenochloride RhCl4Se6S9 and the products of its thermal decomposition are studied by X-ray photoelectron and IR spectroscopies, X-ray powder diffraction, thermal, and elemental analyses. The thermal decomposition of RhCl4Se6S9 was found to occur with a loss of weakly bonded chloro-, sulfur-, and selenium-containing fragments (at 100°C); at the higher temperatures, chlorine is lost and rhodium thioselenides are obtained (Rh4Se4S5 at 490°C and Rh4Se3S5 at 665°C). These changes are attended by the formation of the cluster nucleus [Rh4(µ3-Se)3(µ3-S)]. More... »

PAGES

859-863

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11173-005-0030-5

DOI

http://dx.doi.org/10.1007/s11173-005-0030-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018446114


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pekhno", 
        "givenName": "V. I.", 
        "id": "sg:person.07373251743.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07373251743.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Stepanenko", 
        "givenName": "I. N.", 
        "id": "sg:person.010766212743.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010766212743.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Volkov", 
        "givenName": "S. V.", 
        "id": "sg:person.0777572327.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777572327.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fokina", 
        "givenName": "Z. A.", 
        "id": "sg:person.014021214103.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014021214103.41"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Metal Physics, National Academy of Sciences of Ukraine, pr. Vernadskogo, 36, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Institute of Metal Physics, National Academy of Sciences of Ukraine, pr. Vernadskogo, 36, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korduban", 
        "givenName": "A. M.", 
        "id": "sg:person.016560475301.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016560475301.01"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2004-12", 
    "datePublishedReg": "2004-12-01", 
    "description": "The structure of rhodium thioselenochloride RhCl4Se6S9 and the products of its thermal decomposition are studied by X-ray photoelectron and IR spectroscopies, X-ray powder diffraction, thermal, and elemental analyses. The thermal decomposition of RhCl4Se6S9 was found to occur with a loss of weakly bonded chloro-, sulfur-, and selenium-containing fragments (at 100\u00b0C); at the higher temperatures, chlorine is lost and rhodium thioselenides are obtained (Rh4Se4S5 at 490\u00b0C and Rh4Se3S5 at 665\u00b0C). These changes are attended by the formation of the cluster nucleus [Rh4(\u00b53-Se)3(\u00b53-S)].", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s11173-005-0030-5", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "0132-344X"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "30"
      }
    ], 
    "keywords": [
      "thermal decomposition", 
      "selenium-containing fragments", 
      "ray powder diffraction", 
      "IR spectroscopy", 
      "elemental analysis", 
      "ray photoelectron", 
      "thermal conversion products", 
      "powder diffraction", 
      "conversion products", 
      "high temperature", 
      "spectroscopy", 
      "decomposition", 
      "diffraction", 
      "chloro", 
      "cluster nuclei", 
      "products", 
      "sulfur", 
      "chlorine", 
      "photoelectron", 
      "properties", 
      "formation", 
      "structure", 
      "temperature", 
      "fragments", 
      "analysis", 
      "changes", 
      "loss", 
      "nucleus", 
      "rhodium thioselenochloride RhCl4Se6S9", 
      "thioselenochloride RhCl4Se6S9", 
      "RhCl4Se6S9", 
      "rhodium thioselenides", 
      "thioselenides"
    ], 
    "name": "Some properties of rhodium thioselenochloride RhCl4Se6S9 and its thermal conversion products", 
    "pagination": "859-863", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1018446114"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11173-005-0030-5"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11173-005-0030-5", 
      "https://app.dimensions.ai/details/publication/pub.1018446114"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:07", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_388.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s11173-005-0030-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11173-005-0030-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11173-005-0030-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11173-005-0030-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11173-005-0030-5'


 

This table displays all metadata directly associated to this object as RDF triples.

121 TRIPLES      21 PREDICATES      59 URIs      51 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11173-005-0030-5 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N7da91653fcd7461292bb88431ece0df9
4 schema:datePublished 2004-12
5 schema:datePublishedReg 2004-12-01
6 schema:description The structure of rhodium thioselenochloride RhCl4Se6S9 and the products of its thermal decomposition are studied by X-ray photoelectron and IR spectroscopies, X-ray powder diffraction, thermal, and elemental analyses. The thermal decomposition of RhCl4Se6S9 was found to occur with a loss of weakly bonded chloro-, sulfur-, and selenium-containing fragments (at 100°C); at the higher temperatures, chlorine is lost and rhodium thioselenides are obtained (Rh4Se4S5 at 490°C and Rh4Se3S5 at 665°C). These changes are attended by the formation of the cluster nucleus [Rh4(µ3-Se)3(µ3-S)].
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N0aa69d14328345d794f938a221bfd7b7
11 N32b965c25b18465c82aefad312bd1ba8
12 sg:journal.1294773
13 schema:keywords IR spectroscopy
14 RhCl4Se6S9
15 analysis
16 changes
17 chlorine
18 chloro
19 cluster nuclei
20 conversion products
21 decomposition
22 diffraction
23 elemental analysis
24 formation
25 fragments
26 high temperature
27 loss
28 nucleus
29 photoelectron
30 powder diffraction
31 products
32 properties
33 ray photoelectron
34 ray powder diffraction
35 rhodium thioselenides
36 rhodium thioselenochloride RhCl4Se6S9
37 selenium-containing fragments
38 spectroscopy
39 structure
40 sulfur
41 temperature
42 thermal conversion products
43 thermal decomposition
44 thioselenides
45 thioselenochloride RhCl4Se6S9
46 schema:name Some properties of rhodium thioselenochloride RhCl4Se6S9 and its thermal conversion products
47 schema:pagination 859-863
48 schema:productId N5b0f06f74a6c4ec3909c77df28ce3554
49 Ndbbaa94f21654b579285f59480c0b584
50 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018446114
51 https://doi.org/10.1007/s11173-005-0030-5
52 schema:sdDatePublished 2021-11-01T18:07
53 schema:sdLicense https://scigraph.springernature.com/explorer/license/
54 schema:sdPublisher N56c4211dd2de4a60ac59fdcbb4d3c2eb
55 schema:url https://doi.org/10.1007/s11173-005-0030-5
56 sgo:license sg:explorer/license/
57 sgo:sdDataset articles
58 rdf:type schema:ScholarlyArticle
59 N0aa69d14328345d794f938a221bfd7b7 schema:issueNumber 12
60 rdf:type schema:PublicationIssue
61 N32b965c25b18465c82aefad312bd1ba8 schema:volumeNumber 30
62 rdf:type schema:PublicationVolume
63 N56c4211dd2de4a60ac59fdcbb4d3c2eb schema:name Springer Nature - SN SciGraph project
64 rdf:type schema:Organization
65 N5b0f06f74a6c4ec3909c77df28ce3554 schema:name doi
66 schema:value 10.1007/s11173-005-0030-5
67 rdf:type schema:PropertyValue
68 N6e85af0012ff43cb92ad10c69fde5d91 rdf:first sg:person.010766212743.46
69 rdf:rest Nef7be376fd984eb98c4e3c80a48123c0
70 N7da91653fcd7461292bb88431ece0df9 rdf:first sg:person.07373251743.31
71 rdf:rest N6e85af0012ff43cb92ad10c69fde5d91
72 Nb5d6c961751e4cafa9a9ebf56f494560 rdf:first sg:person.016560475301.01
73 rdf:rest rdf:nil
74 Nb653f72c52f844cd9b3cf8fe5241997e rdf:first sg:person.014021214103.41
75 rdf:rest Nb5d6c961751e4cafa9a9ebf56f494560
76 Ndbbaa94f21654b579285f59480c0b584 schema:name dimensions_id
77 schema:value pub.1018446114
78 rdf:type schema:PropertyValue
79 Nef7be376fd984eb98c4e3c80a48123c0 rdf:first sg:person.0777572327.37
80 rdf:rest Nb653f72c52f844cd9b3cf8fe5241997e
81 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
82 schema:name Chemical Sciences
83 rdf:type schema:DefinedTerm
84 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
85 schema:name Physical Chemistry (incl. Structural)
86 rdf:type schema:DefinedTerm
87 sg:journal.1294773 schema:issn 0132-344X
88 1070-3284
89 schema:name Russian Journal of Coordination Chemistry
90 schema:publisher Springer Nature
91 rdf:type schema:Periodical
92 sg:person.010766212743.46 schema:affiliation grid-institutes:grid.418751.e
93 schema:familyName Stepanenko
94 schema:givenName I. N.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010766212743.46
96 rdf:type schema:Person
97 sg:person.014021214103.41 schema:affiliation grid-institutes:grid.418751.e
98 schema:familyName Fokina
99 schema:givenName Z. A.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014021214103.41
101 rdf:type schema:Person
102 sg:person.016560475301.01 schema:affiliation grid-institutes:grid.418751.e
103 schema:familyName Korduban
104 schema:givenName A. M.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016560475301.01
106 rdf:type schema:Person
107 sg:person.07373251743.31 schema:affiliation grid-institutes:grid.418751.e
108 schema:familyName Pekhno
109 schema:givenName V. I.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07373251743.31
111 rdf:type schema:Person
112 sg:person.0777572327.37 schema:affiliation grid-institutes:grid.418751.e
113 schema:familyName Volkov
114 schema:givenName S. V.
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777572327.37
116 rdf:type schema:Person
117 grid-institutes:grid.418751.e schema:alternateName Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine
118 Institute of Metal Physics, National Academy of Sciences of Ukraine, pr. Vernadskogo, 36, Kiev, Ukraine
119 schema:name Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine
120 Institute of Metal Physics, National Academy of Sciences of Ukraine, pr. Vernadskogo, 36, Kiev, Ukraine
121 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...