Some properties of rhodium thioselenochloride RhCl4Se6S9 and its thermal conversion products View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-12

AUTHORS

V. I. Pekhno, I. N. Stepanenko, S. V. Volkov, Z. A. Fokina, A. M. Korduban

ABSTRACT

The structure of rhodium thioselenochloride RhCl4Se6S9 and the products of its thermal decomposition are studied by X-ray photoelectron and IR spectroscopies, X-ray powder diffraction, thermal, and elemental analyses. The thermal decomposition of RhCl4Se6S9 was found to occur with a loss of weakly bonded chloro-, sulfur-, and selenium-containing fragments (at 100°C); at the higher temperatures, chlorine is lost and rhodium thioselenides are obtained (Rh4Se4S5 at 490°C and Rh4Se3S5 at 665°C). These changes are attended by the formation of the cluster nucleus [Rh4(µ3-Se)3(µ3-S)]. More... »

PAGES

859-863

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11173-005-0030-5

DOI

http://dx.doi.org/10.1007/s11173-005-0030-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018446114


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