Effect of increasing pressure on the structure and temperature-induced changes in magnetic properties of heterospin complexes View Full Text


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Article Info

DATE

2020-08

AUTHORS

G. V. Romanenko, G. A. Letyagin, K. Yu. Maryunina, A. S. Bogomyakov, S. Nishihara, K. Inoue, V. I. Ovcharenko

ABSTRACT

The study is concerned with structural rearrangements in the crystals of heterospin complexes Cu(hfac)2 with nitroxide radicals LR (hfac is hexafluoroacetylacetonate, LR is 2-(1-R-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, R is Et or Allyl) induced by increasing pressure from 10−4 to ∼1 GPa in the pressure-transmitting medium. An increase in the external pressure to only ∼0.03 GPa leads to the disappearance of the temperature-induced magnetic anomaly observed for these heterospin crystals under ambient conditions. More... »

PAGES

1530-1536

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-020-2932-2

DOI

http://dx.doi.org/10.1007/s11172-020-2932-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1130964511


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