Novel oligo-m-carboranylenemethylenesilanes View Full Text


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Article Info

DATE

2020-06

AUTHORS

B. A. Izmaylov, V. A. Vasnev, G. D. Markova

ABSTRACT

A method has been developed for the obtaining of new oligo(dimethyl)silanes comprising 1,7-bis(methyl)-m-carboranyl units and bearing the terminal chlorosilyl or methoxysilyl groups. Reactions of such oligomers with an excess of benzylmagnesium chloride or 1-chloromagnesiummethyl-m-carborane lead to oligo-m-carboranylenemethylenesilanes containing the terminal benzylsilyl or m-carboranylmethylenesilyl groups. The novel oligomers are highly viscous liquids possessing a high heat resistance and also a resistance towards the treatment with a strong alkaline reagent. More... »

PAGES

1130-1133

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-020-2878-4

DOI

http://dx.doi.org/10.1007/s11172-020-2878-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1129501974


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