Reactivity of an aluminum hydride complex with a redox-active diimine ligand View Full Text


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Article Info

DATE

2018-12

AUTHORS

V. G. Sokolov, T. S. Koptseva, V. A. Dodonov, R. V. Rumyantsev, I. L. Fedushkin

ABSTRACT

The reaction of the hydride [(dpp-bian)Al(H)Cl] (1) containing the 1,2-bis[(2,6-diisopropylphenyl) imino]acenaphthene (dpp-bian) radical anion with MeLi affords the compound [(dpp-bian)Al(H)Me] (2). The reaction of complex 1 with two equivalents of PhC≡CNa involves the replacement of chlorine along with oxidative substitution of hydrogen accompanied by the reduction of dpp-bian to the dianion to form the compound [(dpp-bian)Al(C≡CPh)2Na(Et2O)2] ({sn3}). This reaction gives the complex [{dpp-bian(H)}Al(C≡CPh)3Na(Et2O)2] (4) as the second product, which is apparently generated in the reaction of compound 3 with PhC≡CH. The reaction of compound 1 with Cp*Na (Cp* is pentamethylcyclopentadiene) in dimethoxyethane is also accompanied by the reduction of redox-active dpp-bian to the dianion, giving the complex [(dpp-bian)Al(H)Cl][Na(DME)3] (5). Diamagnetic derivatives 3–5 were characterized by 1H NMR spectroscopy; paramagnetic compound 2, by EPR spectroscopy. The molecular structures of compounds 2–5 were determined by X-ray diffraction. More... »

PAGES

2164-2171

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-018-2349-3

DOI

http://dx.doi.org/10.1007/s11172-018-2349-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111893838


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