New disiloxane based on N-acetylvaline: synthesis and structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-08

AUTHORS

A. A. Nikolin, A. A. Korlyukov, E. P. Kramarova, D. E. Arkhipov, A. G. Shipov, Yu. I. Baukov, Vad. V. Negrebetsky

ABSTRACT

Silylmethylation of N-acetylvaline with the ClCH2SiMe2Cl—(Me3Si)2NH system gave the previously unknown 2-silamorpholin-6-one derivative, whose hydrolysis in aqueous ethanol produced bis-acetylvaline-containing disiloxane. The X-ray diffraction study and quantum chemical calculations demonstrated that both silicon atoms in the final product are four-coordinated.

PAGES

1504-1507

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-018-2247-8

DOI

http://dx.doi.org/10.1007/s11172-018-2247-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107798432


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