Quantitative studies of DNA binding with trans complexes of PtII and PdII featuring tetrazolylacetic acids and their derivatives as ligands View Full Text


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Article Info

DATE

2018-07

AUTHORS

O. V. Mikolaichuk, A. V. Protas, E. A. Popova, A. V. Mukhametshina, G. K. Ovsepyan, R. E. Trifonov

ABSTRACT

The interaction of calf thymus DNA (CT DNA) with trans-[PtCl2L2] and trans-[PdCl2L2] complexes (L–5-methyl-1H-tetrazol-1-ylacetic acid and its ethyl, butyl, and isobutyl esters; ethyl esters of 2-R-2H-tetrazol-5-ylacetic acids, R = But, CH2CH2OH) have been quantitatively studied by a spectrophotometric method. The binding constants (Kb) of the tetrazolecontaining coordination compounds with CT DNA at pH 7.2 and 298 K are in the range of (3.67–5.93)•105 mol L–1 for the PdII complexes and (7.82–13.30)•105 mol L–1 for and the PtII complexes, respectively. The Kb values, as well as negative values of ΔGb (–(31.7–34.9) kJ mol–1) indicate the effective binding between the studied complexes and CT DNA. More... »

PAGES

1312-1315

References to SciGraph publications

  • 2012-04. Medicinal chemistry of tetrazoles in RUSSIAN CHEMICAL BULLETIN
  • 2009. Studies on New Platinum Compounds in PLATINUM AND OTHER HEAVY METAL COMPOUNDS IN CANCER CHEMOTHERAPY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-018-2217-1

    DOI

    http://dx.doi.org/10.1007/s11172-018-2217-1

    DIMENSIONS

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