New ruthenocene-based ruthenium pincer complex bearing the C5Me4CF3 ligand View Full Text


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Article Info

DATE

2018-07

AUTHORS

S. V. Safronov, A. A. Koridze

ABSTRACT

The first (trifluoromethyl)tetramethylruthenocene-based ruthenium pincer complex RuCl(CO)[{2,5-(Bu2tPCH2)2C5H2}Ru(C5Me4CF3)] was synthesized by cyclometallation of the bisphosphine ligand {1,3-(Bu2tPCH2)2C5H2}Ru(C5Me4CF3) with RuCl2(DMSO)4 in 2-methoxyethanol in the presence of NEt3. The new complex was fully characterized by 1H, 19F, 31P{1H}, 13C{1H} NMR and IR spectroscopy.

PAGES

1247-1250

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-018-2208-2

DOI

http://dx.doi.org/10.1007/s11172-018-2208-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107353056


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