DFT study of Raman scattering spectra of complexes of spiropyrans with the silver cluster View Full Text


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Article Info

DATE

2018-06

AUTHORS

A. A. Starikova, B. S. Lukyanov, E. L. Mukhanov, O. A. Komissarova, G. T. Vasilyuk, S. A. Maskevich, V. I. Minkin

ABSTRACT

The computational simulation of structure, energy and spectral characteristics of spiropyrans and their complexes with the cluster containing ten silver atoms was carried out using the density functional theory method (B3LYP/6-31G(d,p)/SDD). A competitive coordination of oxygen-containing substituents in the indoline and benzopyran moieties in spirocyclic molecules to the metal atoms was studied and an effect of position of donor groups on the activity of CO vibrational bands was established in the calculated Raman spectra. We revealed compounds, whose trans-trans-trans isomers upon a complexation with the silver cluster are characterized by the more than 100 times enhanced activity of band associated with the valence vibrations of CO bond in the Raman spectrum. More... »

PAGES

972-979

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-018-2166-8

DOI

http://dx.doi.org/10.1007/s11172-018-2166-8

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https://app.dimensions.ai/details/publication/pub.1107262996


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