Homoannular disubstituted ruthenocenes containing a trifluoromethyl(tetramethyl)cyclopentadienyl ligand View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-02

AUTHORS

S. V. Safronov, A. A. Pavlov, V. I. Sokolov, A. A. Koridze

ABSTRACT

The reaction of the divalent ruthenium complexes [CpFRuCl]n and [CpFRu(MeCN)3]PF6 with substituted pentafulvenes 1,2-(Me2NCH)(CO2Et)C5H3 and 1,3-(Me2NCH)(CO2Et)- C5H3 followed by hydrolysis affords new homoannular disubstituted ruthenocenes {1,2- (CO2Et)(CHO)C5H3}RuCpF and {1,3-(CO2Et)(CHO)C5H3}RuCpF (CpF = C5Me4CF3), re- spectively.

PAGES

255-259

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-018-2067-x

DOI

http://dx.doi.org/10.1007/s11172-018-2067-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1103737460


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