Synthesis, structure, and magnetic properties of a YbIII complex with the iminopyridine radical-anionic ligand View Full Text


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Article Info

DATE

2018-01

AUTHORS

A. A. Trifonov, B. G. Shestakov, D. M. Lyubov, K. A. Lyssenko

ABSTRACT

The reaction of equimolar amounts of ytterbocene (C5Me4H)2Yb(THF)2 and iminopyridine 2,6-Pri2C6H3N=CH(C5H4N) accompanied by the one-electron oxidation of the ytterbium ion produced the unique lanthanide complex (C5Me4H)2YbIII[2,6-Pri2-C6H3NCH(C5H4N)]–• with the iminopyridine radical-anionic ligand. The structure of the complex in the crystalline state was established by X-ray diffraction and its magnetic properties were studied in the temperature range of 1.8—300 K. More... »

PAGES

50-55

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-018-2036-4

DOI

http://dx.doi.org/10.1007/s11172-018-2036-4

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https://app.dimensions.ai/details/publication/pub.1103457905


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