Coordination chemistry of anticrowns. Synthesis and structure of a complex of cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 with tungsten hexacarbonyl View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-01

AUTHORS

K. I. Tugashov, S. M. Yunusov, E. S. Kalyuzhnaya, F. M. Dolgushin, A. A. Yakovenko, I. A. Tikhonova, V. B. Shur

ABSTRACT

The reaction of the three-mercury anticrown (o-C6F4Hg)3 (1) with tungsten hexacarbonyl in CH2Cl2 at 20 °C in the dark affords the complex {[(o-C6F4Hg)3]2[W(CO)6]} (2) containing two anticrown molecules per W(CO)6 molecule. According to the X-ray diffraction data, two carbonyl groups of W(CO)6 are involved in the formation of 2, each of these carbonyl groups being coordinated via the oxygen atom to a single mercury center of one of the two molecules 1. The formation of the complex is accompanied by a shift of ν(CO) bands in the IR spectrum with respect to the corresponding bands of the starting W(CO)6. More... »

PAGES

45-49

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-018-2035-5

DOI

http://dx.doi.org/10.1007/s11172-018-2035-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1103479128


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