Reduction of (1,3-diformylindenyl)cyclopentadienylruthenium derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-01

AUTHORS

S. V. Safronov, S. A. Kuklin, A. M. Sheloumov, A. A. Kamyshova, A. A. Koridze

ABSTRACT

The reduction of the (1,3-diformylindenyl)cyclopentadienylruthenium derivatives {η5-1,3-(CHO)2C9H5}RuCp (Cp = C5H5), {η5-1,3-(CHO)2C9H5}RuCp* (Cp* = C5Me5), and {η5-1,3-(CHO)2C9H5}RuCpF (CpF = C5Me4CF3) with NaBH4 or LiAlH4 under mild conditions affords the [1,3-bis(hydroxymethyl)indenyl]cyclopentadienylruthenium complexes {η5-1,3-(CH2OH)2C9H5}RuCp, {η5-1,3-(CH2OH)2C9H5}RuCp*, and {η5-1,3-(CH2OH)2C9H5}-RuCpF, respectively, in good yields.

PAGES

33-35

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-018-2033-7

DOI

http://dx.doi.org/10.1007/s11172-018-2033-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1103459263


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