Fe-containing nanocomposites based on a biocompatible copolymer 1-vinyl-1,2,4-triazole with N-vinylpyrrolidone View Full Text


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Article Info

DATE

2017-12

AUTHORS

A. S. Pozdnyakov, A. A. Ivanova, A. I. Emel’yanov, S. S. Khutsishvili, T. I. Vakul’skaya, T. G. Ermakova, G. F. Prozorova

ABSTRACT

New polymer nanocomposites containing iron oxide nanoparticles stabilized with a biocompatible copolymer of 1-vinyl-1,2,4-triazole with N-vinylpyrrolidone were produced. The synthesis was conducted using the method of chemical reduction of iron ions with hydrazine hydrate in an aqueous medium in the presence of a polymer matrix. The ESR spectroscopy data showed that the core—shell type nanoparticles were obtained. The core generally consistsed of zero-valence iron coated with an oxide shell. According to the data of transmission electron microscopy, the obtained polymer nanocomposites consisted of nanoparticles of mainly spherical shape with a diameter from 1 to 14 nm. Aggregates formed from individual stabilized nanoparticles of up to 75 nm in size (in most cases) were also observed. These aggregated particles were found to self-organize and form branched chains. Nanocomposites were characterized by a different particle-size distribution, which was determined by the initial ratio of the copolymer and the precursor of iron nanoparticles. More... »

PAGES

2308-2313

References to SciGraph publications

  • 2015-06. Mechanism of formation of silver nanoparticles in MAG–DMAEMA copolymer aqueous solutions in JOURNAL OF NANOPARTICLE RESEARCH
  • 2015-02. New water-soluble silver nanocomposites in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2004-05. The Nature and Properties of Iron-Containing Nanoparticles Dispersed in an Aluminosilicate Matrix of Cenospheres in GLASS PHYSICS AND CHEMISTRY
  • 2014-09. Toxicity evaluation of polyvinyltriazole and a related silver-containing nanocomposite in RUSSIAN CHEMICAL BULLETIN
  • 2017-06. Nanocomposites with silver nanoparticles based on copolymer of 1-vinyl-1,2,4-triazole with N-vinylpyrrolidone in RUSSIAN CHEMICAL BULLETIN
  • 2003-07. Synthesis of \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$\mathsf{\gamma}$\end{document}-Fe\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$\mathsf{_2}$\end{document}O\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$\mathsf{_3}$\end{document} nanoparticles coated on silica spheres: Structural and magnetic properties in THE EUROPEAN PHYSICAL JOURNAL B
  • 2016-09. Synthesis of hybrid materials in polyelectrolyte matrixes: Control over sizes and spatial organization of metallic nanostructures in POLYMER SCIENCE, SERIES C
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    http://scigraph.springernature.com/pub.10.1007/s11172-017-2020-4

    DOI

    http://dx.doi.org/10.1007/s11172-017-2020-4

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