Ontology type: schema:ScholarlyArticle
2017-12
AUTHORSS. N. Tandura, V. V. Belyaeva, B. A. Gostevskii, A. I. Albanov
ABSTRACTA new mechanism of the dipole—induced dipole polarization interaction was considered to explain an anomalous increase in the +I effect in a 1-phenylsilatrane molecule with the pentacoordinated Si atom. The interaction through the space between the silatrane cage having a high dipole moment and easily polarizable aromatic phenyl substituent induces dipole that adds the influence of the inductive effect along the bonds, which is characteristic of usual silatranes. The high inductive constant σI calculated for 1-phenylsilatrane on the basis of chemical shifts δC of aromatic carbon atoms was interpreted as a superelectronodonor effect in silatranes. However, the polarization effect through the space leads to a substantial change in the chemical shifts δC for the phenyl group in the direction that formally corresponds to the enhancement of the +I effect transmitted via the bonds. It is shown for the first time that the inductive effect in silatranes is not constant and varies according to the polarizability of the substituent at the Si atom. More... »
PAGES2269-2275
http://scigraph.springernature.com/pub.10.1007/s11172-017-2013-3
DOIhttp://dx.doi.org/10.1007/s11172-017-2013-3
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1101543545
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Tandura",
"givenName": "S. N.",
"id": "sg:person.012124634075.11",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012124634075.11"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Belyaeva",
"givenName": "V. V.",
"id": "sg:person.013603175435.69",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013603175435.69"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Gostevskii",
"givenName": "B. A.",
"id": "sg:person.011255175572.24",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011255175572.24"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Albanov",
"givenName": "A. I.",
"id": "sg:person.0754654523.04",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0754654523.04"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/978-3-540-45278-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1003548054",
"https://doi.org/10.1007/978-3-540-45278-2"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1070363206120024",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025380546",
"https://doi.org/10.1134/s1070363206120024"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1023/a:1023403026676",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026794946",
"https://doi.org/10.1023/a:1023403026676"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1070363214010101",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1000918311",
"https://doi.org/10.1134/s1070363214010101"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1023/a:1011356202557",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039768396",
"https://doi.org/10.1023/a:1011356202557"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s11172-009-0004-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1044089887",
"https://doi.org/10.1007/s11172-009-0004-8"
],
"type": "CreativeWork"
}
],
"datePublished": "2017-12",
"datePublishedReg": "2017-12-01",
"description": "A new mechanism of the dipole\u2014induced dipole polarization interaction was considered to explain an anomalous increase in the +I effect in a 1-phenylsilatrane molecule with the pentacoordinated Si atom. The interaction through the space between the silatrane cage having a high dipole moment and easily polarizable aromatic phenyl substituent induces dipole that adds the influence of the inductive effect along the bonds, which is characteristic of usual silatranes. The high inductive constant \u03c3I calculated for 1-phenylsilatrane on the basis of chemical shifts \u03b4C of aromatic carbon atoms was interpreted as a superelectronodonor effect in silatranes. However, the polarization effect through the space leads to a substantial change in the chemical shifts \u03b4C for the phenyl group in the direction that formally corresponds to the enhancement of the +I effect transmitted via the bonds. It is shown for the first time that the inductive effect in silatranes is not constant and varies according to the polarizability of the substituent at the Si atom.",
"genre": "article",
"id": "sg:pub.10.1007/s11172-017-2013-3",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1026-3500",
"1066-5285"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "12",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "66"
}
],
"keywords": [
"Si atoms",
"polarization effects",
"polarization interaction",
"dipole moment",
"atoms",
"high dipole moment",
"anomalous increase",
"chemical shifts",
"carbon atoms",
"polarizability",
"new mechanism",
"dipole",
"first time",
"interaction",
"moment",
"bonds",
"silatranes",
"donor properties",
"space",
"inductive effect",
"aromatic carbon atoms",
"shift",
"enhancement",
"properties",
"molecules",
"\u03c3i",
"\u0394C",
"phenyl group",
"direction",
"effect",
"substantial changes",
"influence",
"time",
"mechanism",
"cages",
"basis",
"substituents",
"increase",
"changes",
"group"
],
"name": "Influence of the polarization effect on the donor properties of 1-phenylsilatrane",
"pagination": "2269-2275",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1101543545"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s11172-017-2013-3"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s11172-017-2013-3",
"https://app.dimensions.ai/details/publication/pub.1101543545"
],
"sdDataset": "articles",
"sdDatePublished": "2022-06-01T22:16",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_741.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/s11172-017-2013-3"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-017-2013-3'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-017-2013-3'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-017-2013-3'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-017-2013-3'
This table displays all metadata directly associated to this object as RDF triples.
142 TRIPLES
22 PREDICATES
71 URIs
58 LITERALS
6 BLANK NODES