Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-11

AUTHORS

A. I. Lazareva, I. V. Pisareva, E. V. Balagurova, A. F. Smolyakov, F. M. Dolgushin, I. A. Godovikov, I. T. Chizhevsky

ABSTRACT

The anionic manganese tricarbonyl complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C2B8H12 with Mn(CO)5Br. The structure of the complex [tmdaH][1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10] was deter-mined by X-ray diffraction.

PAGES

2142-2144

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-017-1994-2

DOI

http://dx.doi.org/10.1007/s11172-017-1994-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101534857


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lazareva", 
        "givenName": "A. I.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pisareva", 
        "givenName": "I. V.", 
        "id": "sg:person.01223207225.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01223207225.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Balagurova", 
        "givenName": "E. V.", 
        "id": "sg:person.014563340706.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014563340706.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Physics and Mathematics and Natural Sciences, Peoples\u2019 Friendship University of Russia, 6 ul. Miklukho-Maklaya, 117198, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.77642.30", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation", 
            "Faculty of Physics and Mathematics and Natural Sciences, Peoples\u2019 Friendship University of Russia, 6 ul. Miklukho-Maklaya, 117198, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Smolyakov", 
        "givenName": "A. F.", 
        "id": "sg:person.013211030045.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013211030045.88"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dolgushin", 
        "givenName": "F. M.", 
        "id": "sg:person.01267101640.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01267101640.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Godovikov", 
        "givenName": "I. A.", 
        "id": "sg:person.01110062307.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01110062307.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chizhevsky", 
        "givenName": "I. T.", 
        "id": "sg:person.0611610740.32", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0611610740.32"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/b:rucb.0000019893.92029.55", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016029822", 
          "https://doi.org/10.1023/b:rucb.0000019893.92029.55"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00962002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048395670", 
          "https://doi.org/10.1007/bf00962002"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-11", 
    "datePublishedReg": "2017-11-01", 
    "description": "The anionic manganese tricarbonyl complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]\u2013was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N\u2019,N\u2019-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C2B8H12 with Mn(CO)5Br. The structure of the complex [tmdaH][1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10] was deter-mined by X-ray diffraction.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s11172-017-1994-2", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1063-5211", 
          "1026-3500"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "66"
      }
    ], 
    "keywords": [
      "manganese tricarbonyl complexes", 
      "tricarbonyl complexes", 
      "molecular structure", 
      "ray diffraction", 
      "carborane", 
      "complexes", 
      "diffraction", 
      "salt", 
      "synthesis", 
      "structure", 
      "reaction", 
      "PPN", 
      "form", 
      "anionic manganese tricarbonyl complex", 
      "form of PPN", 
      "tmdaH salts", 
      "medium-size non-icosahedral carborane", 
      "non-icosahedral carborane", 
      "C2B8H12", 
      "C2B8H12 carborane"
    ], 
    "name": "Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane", 
    "pagination": "2142-2144", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1101534857"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-017-1994-2"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-017-1994-2", 
      "https://app.dimensions.ai/details/publication/pub.1101534857"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:44", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_743.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s11172-017-1994-2"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-017-1994-2'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-017-1994-2'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-017-1994-2'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-017-1994-2'


 

This table displays all metadata directly associated to this object as RDF triples.

131 TRIPLES      22 PREDICATES      48 URIs      38 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-017-1994-2 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N26cc33dd1aa44c1788fa9521d136cb18
4 schema:citation sg:pub.10.1007/bf00962002
5 sg:pub.10.1023/b:rucb.0000019893.92029.55
6 schema:datePublished 2017-11
7 schema:datePublishedReg 2017-11-01
8 schema:description The anionic manganese tricarbonyl complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C2B8H12 with Mn(CO)5Br. The structure of the complex [tmdaH][1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10] was deter-mined by X-ray diffraction.
9 schema:genre article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N3d284d2ef712415b855ea43912429788
13 Ne01a26aa85f3405985e43ef0f73ea789
14 sg:journal.1022309
15 schema:keywords C2B8H12
16 C2B8H12 carborane
17 PPN
18 anionic manganese tricarbonyl complex
19 carborane
20 complexes
21 diffraction
22 form
23 form of PPN
24 manganese tricarbonyl complexes
25 medium-size non-icosahedral carborane
26 molecular structure
27 non-icosahedral carborane
28 ray diffraction
29 reaction
30 salt
31 structure
32 synthesis
33 tmdaH salts
34 tricarbonyl complexes
35 schema:name Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane
36 schema:pagination 2142-2144
37 schema:productId Nee7b40c67bf24d33aa4b05418b816557
38 Nf4adb4976b21452882bd9e7546ed03ec
39 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101534857
40 https://doi.org/10.1007/s11172-017-1994-2
41 schema:sdDatePublished 2022-01-01T18:44
42 schema:sdLicense https://scigraph.springernature.com/explorer/license/
43 schema:sdPublisher Nb232c502234c4bcdab883921a84c3eeb
44 schema:url https://doi.org/10.1007/s11172-017-1994-2
45 sgo:license sg:explorer/license/
46 sgo:sdDataset articles
47 rdf:type schema:ScholarlyArticle
48 N171afff094864d1e8ef6792b816ff8e7 rdf:first sg:person.0611610740.32
49 rdf:rest rdf:nil
50 N26cc33dd1aa44c1788fa9521d136cb18 rdf:first N7161b27ab72a453eabc85d207500a424
51 rdf:rest Nd1a220a0f9a7423583bf00ec59a083ca
52 N3d284d2ef712415b855ea43912429788 schema:volumeNumber 66
53 rdf:type schema:PublicationVolume
54 N7161b27ab72a453eabc85d207500a424 schema:affiliation grid-institutes:grid.431939.5
55 schema:familyName Lazareva
56 schema:givenName A. I.
57 rdf:type schema:Person
58 N71d59a853ebe4a24a7a2074b148bcd59 rdf:first sg:person.01110062307.12
59 rdf:rest N171afff094864d1e8ef6792b816ff8e7
60 N82ab73e415194f61ac8ed6d5b5ebdf9d rdf:first sg:person.013211030045.88
61 rdf:rest Nc383482fcd53444a90c6408089c57dbb
62 N95654e6c8dfc4b73973c4ad7fa39aa15 rdf:first sg:person.014563340706.93
63 rdf:rest N82ab73e415194f61ac8ed6d5b5ebdf9d
64 Nb232c502234c4bcdab883921a84c3eeb schema:name Springer Nature - SN SciGraph project
65 rdf:type schema:Organization
66 Nc383482fcd53444a90c6408089c57dbb rdf:first sg:person.01267101640.70
67 rdf:rest N71d59a853ebe4a24a7a2074b148bcd59
68 Nd1a220a0f9a7423583bf00ec59a083ca rdf:first sg:person.01223207225.31
69 rdf:rest N95654e6c8dfc4b73973c4ad7fa39aa15
70 Ne01a26aa85f3405985e43ef0f73ea789 schema:issueNumber 11
71 rdf:type schema:PublicationIssue
72 Nee7b40c67bf24d33aa4b05418b816557 schema:name doi
73 schema:value 10.1007/s11172-017-1994-2
74 rdf:type schema:PropertyValue
75 Nf4adb4976b21452882bd9e7546ed03ec schema:name dimensions_id
76 schema:value pub.1101534857
77 rdf:type schema:PropertyValue
78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
79 schema:name Chemical Sciences
80 rdf:type schema:DefinedTerm
81 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
82 schema:name Physical Chemistry (incl. Structural)
83 rdf:type schema:DefinedTerm
84 sg:journal.1022309 schema:issn 1026-3500
85 1063-5211
86 schema:name Russian Chemical Bulletin
87 schema:publisher Springer Nature
88 rdf:type schema:Periodical
89 sg:person.01110062307.12 schema:affiliation grid-institutes:grid.431939.5
90 schema:familyName Godovikov
91 schema:givenName I. A.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01110062307.12
93 rdf:type schema:Person
94 sg:person.01223207225.31 schema:affiliation grid-institutes:grid.431939.5
95 schema:familyName Pisareva
96 schema:givenName I. V.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01223207225.31
98 rdf:type schema:Person
99 sg:person.01267101640.70 schema:affiliation grid-institutes:grid.431939.5
100 schema:familyName Dolgushin
101 schema:givenName F. M.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01267101640.70
103 rdf:type schema:Person
104 sg:person.013211030045.88 schema:affiliation grid-institutes:grid.77642.30
105 schema:familyName Smolyakov
106 schema:givenName A. F.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013211030045.88
108 rdf:type schema:Person
109 sg:person.014563340706.93 schema:affiliation grid-institutes:grid.431939.5
110 schema:familyName Balagurova
111 schema:givenName E. V.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014563340706.93
113 rdf:type schema:Person
114 sg:person.0611610740.32 schema:affiliation grid-institutes:grid.431939.5
115 schema:familyName Chizhevsky
116 schema:givenName I. T.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0611610740.32
118 rdf:type schema:Person
119 sg:pub.10.1007/bf00962002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048395670
120 https://doi.org/10.1007/bf00962002
121 rdf:type schema:CreativeWork
122 sg:pub.10.1023/b:rucb.0000019893.92029.55 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016029822
123 https://doi.org/10.1023/b:rucb.0000019893.92029.55
124 rdf:type schema:CreativeWork
125 grid-institutes:grid.431939.5 schema:alternateName A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
126 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
127 rdf:type schema:Organization
128 grid-institutes:grid.77642.30 schema:alternateName Faculty of Physics and Mathematics and Natural Sciences, Peoples’ Friendship University of Russia, 6 ul. Miklukho-Maklaya, 117198, Moscow, Russian Federation
129 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
130 Faculty of Physics and Mathematics and Natural Sciences, Peoples’ Friendship University of Russia, 6 ul. Miklukho-Maklaya, 117198, Moscow, Russian Federation
131 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...