Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-11

AUTHORS

A. I. Lazareva, I. V. Pisareva, E. V. Balagurova, A. F. Smolyakov, F. M. Dolgushin, I. A. Godovikov, I. T. Chizhevsky

ABSTRACT

The anionic manganese tricarbonyl complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C2B8H12 with Mn(CO)5Br. The structure of the complex [tmdaH][1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10] was deter-mined by X-ray diffraction.

PAGES

2142-2144

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-017-1994-2

DOI

http://dx.doi.org/10.1007/s11172-017-1994-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101534857


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