Synthesis and structure of the first representative of pentacoordinate C,O-chelates with a dipeptide fragment, the fluorosilane Ts—Gly—(S)-Pro—N(Me)CH2SiMe2F View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-03

AUTHORS

A. A. Nikolin, E. P. Kramarova, A. A. Korlyukov, D. E. Arkhipov, A. G. Shipov, Yu. I. Baukov, A. A. Lagunin, T. A. Shmigol, Vad. V. Negrebetsky

ABSTRACT

A reaction of bicyclic 2-sila-5-piperazinone, 2,2,4-trimethyl-1,4-diaza-2-silabicyclo-[4.3.0]nonan-5-one containing a proline moiety, and N-tosylglycine acyl chloride with subsequent hydrolysis of the primary unstable product to the intermediate disiloxane and its treatment with BF3•OEt2 furnished a first representative of pentacoordinate C,O-chelate halosilanes with a dipeptide fragment, namely, Ts—Gly—(S)-Pro—N(Me)CH2SiMe2F.

PAGES

571-573

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-017-1774-z

DOI

http://dx.doi.org/10.1007/s11172-017-1774-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1091411690


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