Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties View Full Text


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Article Info

DATE

2016-12

AUTHORS

S. A. Nikolaevskii, M. A. Kiskin, A. A. Starikova, N. N. Efimov, A. A. Sidorov, V. M. Novotortsev, I. L. Eremenko

ABSTRACT

Two novel binuclear nickel(II) complexes [Ni2(O2CR)4(2,3-lut)2] (O2CR is anion of 3,5-di(tert-butyl)benzoic acid (bzo, 1) and 4-hydroxy-3,5-di(tert-butyl)benzoic acid (hbzo, 2); 2,3-lut is 2,3-lutidine) with four carboxylate bridges were synthesized. The structure of complex 1 was determined by X-ray diffraction. Both dimers 1 and 2 were characterized by elemental analysis, IR spectroscopy, and magnetic measurements. The presence of the α-substituent in the apical lutidine ligand leads to a distortion of the geometry of the metal carboxylate core in complex 1 as a result of short steric contacts Me(Lut)…O(OOCR) (3.134(7) Å). This is apparently responsible for a considerable decrease in the exchange parameters of complexes 1 and 2 (J =–30.0 and–23.6 cm–1, respectively) as compared to known analogues. Density functional calculations of the structure and magnetic properties of 1 and 2 were carried out by the UB3LYP/6-31G(d,p) method. More... »

PAGES

2812-2819

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-016-1661-z

DOI

http://dx.doi.org/10.1007/s11172-016-1661-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1085594927


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