Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-11

AUTHORS

A. A. Sapianik, I. A. Lutsenko, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko, D. G. Samsonenko, D. N. Dybtsev, V. P. Fedin

ABSTRACT

A new heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] (1, piv = –O2CBut, py = pyridine) was synthesized. Its reaction with terephthalic acid (H2bdc) in N,N-dimethylacetamide (DMA) results in metal-organic coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis. The structure of 2 has two types of channels (4×8 Å and 5×16 Å) that are occupied by coordinated and guest DMA molecules. More... »

PAGES

2601-2606

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-016-1624-4

DOI

http://dx.doi.org/10.1007/s11172-016-1624-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1085415865


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