Influence of geometric and electronic features of pyridine derivatives and triethylamine on the formation of a metal carboxylate core in ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-05

AUTHORS

N. V. Gogoleva, M. A. Shmelev, M. A. Kiskin, G. G. Aleksandrov, A. A. Sidorov, I. L. Eremenko

ABSTRACT

The reaction products of [Cd(piv)2] (piv is–O2CBut) with isoquinoline (iqn), 2,4-lutidine (lut), phenanthridine (phend), 2,3-cyclododecenopyridine (cpy), and triethylamine (Et3N) were synthesized and their structures were determined. The steric factors were found to play a more important role in cadmium(ii) pivalate complexes compared to 3d metal carboxylates in the +2 oxidation state. The reaction of [Cd(piv)2] with isoquinoline produces only the mononuclear complex [Cd(piv)2(iqn)3] (1). The reaction of [Cd(piv)2] with pyridine derivatives bearing a bulky substituent at the α position is accompanied by the formation of symmetrical dinuclear complexes of the composition [Cd2(piv)4(L)2]. In the complexes with L = lut (2) or phend (3), the cadmium(ii) atoms are linked by two chelating-bridging carboxylate groups; in the complex with L = cpy (4), by four bidentate-bridging groups. The reaction of [Cd(piv)2] with Et3N in a solution of MeCN gives the centrosymmetric linear trinuclear complex [Cd3(piv)6(Et3N)2] (6); in a mixture of benzene and hexane, the ionic compound (HEt3N)[Cd2(piv)5(H2O)] (7). The crystal structures of all synthesized compounds were determined by X-ray diffraction. More... »

PAGES

1198-1207

References to SciGraph publications

  • 2004-01. Reversible temperature-dependent structural transformations of the Co3(OOCBut)6(NEt3)2 complex in crystalline state in RUSSIAN CHEMICAL BULLETIN
  • 2006-10. Thermal transformations of complexes Co2(μ-OOCBut)4(NEt3)2 and Co3(μ-OOCBut)2(μ-OOCBut)4(NEt3)2 in RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
  • 2006-01. Co(II)-Mediated and microwave assisted coupling between 2,6-diaminopyridine and nitriles. A new synthetic route to N-(6-aminopyridin-2-yl)carboximidamides in RUSSIAN CHEMICAL BULLETIN
  • 2007-09. Thermal decomposition of dinuclear complexes LM(μ-OOCR)4ML (L is α-substituted pyridine) in RUSSIAN CHEMICAL BULLETIN
  • 2001-08. Formation and Transformations of Polynuclear Hydroxo- and Oxotrimethylacetate Complexes of Ni(II) and Co(II) in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • 1999-09. New polynuclear cobalt trimethylacetate complexes: synthesis and structure in RUSSIAN CHEMICAL BULLETIN
  • 1999-03. Trimethylacetate nickel complexes in RUSSIAN CHEMICAL BULLETIN
  • 2003-10. Formation of bi- and tetranuclear cobalt(ii) trimethylacetate complexes with 2-amino-5-methylpyridine and 2,6-diaminopyridine in RUSSIAN CHEMICAL BULLETIN
  • 2000. Structure Determination of Organic Compounds, Tables of Spectral Data in NONE
  • 2005-09. Pivalate Bridged High Spin Manganese(II) and Iron(II) Polymers in JOURNAL OF CLUSTER SCIENCE
  • 2006-08. Synthetic modeling of the active site of native metalloenzymes by trimethylacetatozinc complexes in RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
  • 2010-06. Influence of the nature of organic ligands on the character of thermal decomposition products of CoII and NiII pivalate complexes with amino derivatives of pyridine in RUSSIAN CHEMICAL BULLETIN
  • 2000-11. Synthesis and structures of nickel(II) trimethylacetate dimers with coordinated diamines in RUSSIAN CHEMICAL BULLETIN
  • Journal

    TITLE

    Russian Chemical Bulletin

    ISSUE

    5

    VOLUME

    65

    Author Affiliations

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-016-1436-6

    DOI

    http://dx.doi.org/10.1007/s11172-016-1436-6

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1074214306


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Inorganic Chemistry", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Russian Academy of Sciences", 
              "id": "https://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Gogoleva", 
            "givenName": "N. V.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Russian Academy of Sciences", 
              "id": "https://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Shmelev", 
            "givenName": "M. A.", 
            "id": "sg:person.012055671403.47", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012055671403.47"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Russian Academy of Sciences", 
              "id": "https://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kiskin", 
            "givenName": "M. A.", 
            "id": "sg:person.01172445335.81", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Russian Academy of Sciences", 
              "id": "https://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Aleksandrov", 
            "givenName": "G. G.", 
            "id": "sg:person.016256220664.16", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016256220664.16"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Russian Academy of Sciences", 
              "id": "https://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Sidorov", 
            "givenName": "A. A.", 
            "id": "sg:person.014044746763.06", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014044746763.06"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Russian Academy of Sciences", 
              "id": "https://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Eremenko", 
            "givenName": "I. L.", 
            "id": "sg:person.0745631435.08", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/j.ica.2011.10.056", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000919836"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.ica.2012.03.031", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1003616173"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02496153", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005547948", 
              "https://doi.org/10.1007/bf02496153"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02496153", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005547948", 
              "https://doi.org/10.1007/bf02496153"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02494824", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010704813", 
              "https://doi.org/10.1007/bf02494824"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02494824", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010704813", 
              "https://doi.org/10.1007/bf02494824"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://app.dimensions.ai/details/publication/pub.1013278232", 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-3-662-04201-4", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013278232", 
              "https://doi.org/10.1007/978-3-662-04201-4"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-3-662-04201-4", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013278232", 
              "https://doi.org/10.1007/978-3-662-04201-4"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02494929", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1015160210", 
              "https://doi.org/10.1007/bf02494929"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02494929", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1015160210", 
              "https://doi.org/10.1007/bf02494929"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1107/s0108270192005808", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016420631"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11172-010-0220-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018561253", 
              "https://doi.org/10.1007/s11172-010-0220-2"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11172-010-0220-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018561253", 
              "https://doi.org/10.1007/s11172-010-0220-2"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11172-006-0212-4", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1020586896", 
              "https://doi.org/10.1007/s11172-006-0212-4"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1107/s1600536808005102", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1022365836"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/b711650k", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1022812376"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s0036023606080110", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023636565", 
              "https://doi.org/10.1134/s0036023606080110"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.poly.2006.10.010", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1024331324"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1107/s0108767307043930", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027786902"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.jinorgbio.2014.06.008", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029203820"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/dt9950001519", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029255995"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10876-005-0009-x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1032770944", 
              "https://doi.org/10.1007/s10876-005-0009-x"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10876-005-0009-x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1032770944", 
              "https://doi.org/10.1007/s10876-005-0009-x"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10876-005-0009-x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1032770944", 
              "https://doi.org/10.1007/s10876-005-0009-x"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.mencom.2011.04.017", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1033008721"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.ica.2009.06.035", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035308128"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.poly.2014.03.008", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035423688"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.molstruc.2014.03.052", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1035939028"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s11172-007-0267-x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037839699", 
              "https://doi.org/10.1007/s11172-007-0267-x"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.molstruc.2006.12.013", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039172418"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/b:rucb.0000024860.24003.61", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041713573", 
              "https://doi.org/10.1023/b:rucb.0000024860.24003.61"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/b:rucb.0000011866.57209.5b", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043976446", 
              "https://doi.org/10.1023/b:rucb.0000011866.57209.5b"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/a:1011349727749", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046970222", 
              "https://doi.org/10.1023/a:1011349727749"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/ejic.200900821", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1049080861"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.inoche.2004.11.012", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1049779436"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.poly.2008.09.017", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050149088"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.ica.2011.01.040", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050787284"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.molstruc.2014.07.067", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1051247827"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s0036023606100135", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1051892493", 
              "https://doi.org/10.1134/s0036023606100135"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic00175a023", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055545971"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic050475x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055557865"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic050475x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055557865"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic0522028", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055558894"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic0522028", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055558894"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic981292w", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055589338"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic981292w", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055589338"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00007a028", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055698479"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja9831094", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055870751"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2016-05", 
        "datePublishedReg": "2016-05-01", 
        "description": "The reaction products of [Cd(piv)2] (piv is\u2013O2CBut) with isoquinoline (iqn), 2,4-lutidine (lut), phenanthridine (phend), 2,3-cyclododecenopyridine (cpy), and triethylamine (Et3N) were synthesized and their structures were determined. The steric factors were found to play a more important role in cadmium(ii) pivalate complexes compared to 3d metal carboxylates in the +2 oxidation state. The reaction of [Cd(piv)2] with isoquinoline produces only the mononuclear complex [Cd(piv)2(iqn)3] (1). The reaction of [Cd(piv)2] with pyridine derivatives bearing a bulky substituent at the \u03b1 position is accompanied by the formation of symmetrical dinuclear complexes of the composition [Cd2(piv)4(L)2]. In the complexes with L = lut (2) or phend (3), the cadmium(ii) atoms are linked by two chelating-bridging carboxylate groups; in the complex with L = cpy (4), by four bidentate-bridging groups. The reaction of [Cd(piv)2] with Et3N in a solution of MeCN gives the centrosymmetric linear trinuclear complex [Cd3(piv)6(Et3N)2] (6); in a mixture of benzene and hexane, the ionic compound (HEt3N)[Cd2(piv)5(H2O)] (7). The crystal structures of all synthesized compounds were determined by X-ray diffraction.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/s11172-016-1436-6", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1022309", 
            "issn": [
              "1066-5285", 
              "1573-9171"
            ], 
            "name": "Russian Chemical Bulletin", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "5", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "65"
          }
        ], 
        "name": "Influence of geometric and electronic features of pyridine derivatives and triethylamine on the formation of a metal carboxylate core in reactions producing cadmium(ii) pivalate complexes", 
        "pagination": "1198-1207", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "e319ab50f3b350c405d1dcc69aed0c375ea73509a233d7c75cb96f46a4635268"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s11172-016-1436-6"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1074214306"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s11172-016-1436-6", 
          "https://app.dimensions.ai/details/publication/pub.1074214306"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-11T10:21", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000348_0000000348/records_54336_00000001.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://link.springer.com/10.1007%2Fs11172-016-1436-6"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-016-1436-6'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-016-1436-6'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-016-1436-6'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-016-1436-6'


     

    This table displays all metadata directly associated to this object as RDF triples.

    224 TRIPLES      21 PREDICATES      66 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s11172-016-1436-6 schema:about anzsrc-for:03
    2 anzsrc-for:0302
    3 schema:author Nc802dea463a3492b961411e64e6942ca
    4 schema:citation sg:pub.10.1007/978-3-662-04201-4
    5 sg:pub.10.1007/bf02494824
    6 sg:pub.10.1007/bf02494929
    7 sg:pub.10.1007/bf02496153
    8 sg:pub.10.1007/s10876-005-0009-x
    9 sg:pub.10.1007/s11172-006-0212-4
    10 sg:pub.10.1007/s11172-007-0267-x
    11 sg:pub.10.1007/s11172-010-0220-2
    12 sg:pub.10.1023/a:1011349727749
    13 sg:pub.10.1023/b:rucb.0000011866.57209.5b
    14 sg:pub.10.1023/b:rucb.0000024860.24003.61
    15 sg:pub.10.1134/s0036023606080110
    16 sg:pub.10.1134/s0036023606100135
    17 https://app.dimensions.ai/details/publication/pub.1013278232
    18 https://doi.org/10.1002/ejic.200900821
    19 https://doi.org/10.1016/j.ica.2009.06.035
    20 https://doi.org/10.1016/j.ica.2011.01.040
    21 https://doi.org/10.1016/j.ica.2011.10.056
    22 https://doi.org/10.1016/j.ica.2012.03.031
    23 https://doi.org/10.1016/j.inoche.2004.11.012
    24 https://doi.org/10.1016/j.jinorgbio.2014.06.008
    25 https://doi.org/10.1016/j.mencom.2011.04.017
    26 https://doi.org/10.1016/j.molstruc.2006.12.013
    27 https://doi.org/10.1016/j.molstruc.2014.03.052
    28 https://doi.org/10.1016/j.molstruc.2014.07.067
    29 https://doi.org/10.1016/j.poly.2006.10.010
    30 https://doi.org/10.1016/j.poly.2008.09.017
    31 https://doi.org/10.1016/j.poly.2014.03.008
    32 https://doi.org/10.1021/ic00175a023
    33 https://doi.org/10.1021/ic050475x
    34 https://doi.org/10.1021/ic0522028
    35 https://doi.org/10.1021/ic981292w
    36 https://doi.org/10.1021/ja00007a028
    37 https://doi.org/10.1021/ja9831094
    38 https://doi.org/10.1039/b711650k
    39 https://doi.org/10.1039/dt9950001519
    40 https://doi.org/10.1107/s0108270192005808
    41 https://doi.org/10.1107/s0108767307043930
    42 https://doi.org/10.1107/s1600536808005102
    43 schema:datePublished 2016-05
    44 schema:datePublishedReg 2016-05-01
    45 schema:description The reaction products of [Cd(piv)2] (piv is–O2CBut) with isoquinoline (iqn), 2,4-lutidine (lut), phenanthridine (phend), 2,3-cyclododecenopyridine (cpy), and triethylamine (Et3N) were synthesized and their structures were determined. The steric factors were found to play a more important role in cadmium(ii) pivalate complexes compared to 3d metal carboxylates in the +2 oxidation state. The reaction of [Cd(piv)2] with isoquinoline produces only the mononuclear complex [Cd(piv)2(iqn)3] (1). The reaction of [Cd(piv)2] with pyridine derivatives bearing a bulky substituent at the α position is accompanied by the formation of symmetrical dinuclear complexes of the composition [Cd2(piv)4(L)2]. In the complexes with L = lut (2) or phend (3), the cadmium(ii) atoms are linked by two chelating-bridging carboxylate groups; in the complex with L = cpy (4), by four bidentate-bridging groups. The reaction of [Cd(piv)2] with Et3N in a solution of MeCN gives the centrosymmetric linear trinuclear complex [Cd3(piv)6(Et3N)2] (6); in a mixture of benzene and hexane, the ionic compound (HEt3N)[Cd2(piv)5(H2O)] (7). The crystal structures of all synthesized compounds were determined by X-ray diffraction.
    46 schema:genre research_article
    47 schema:inLanguage en
    48 schema:isAccessibleForFree false
    49 schema:isPartOf N2d86c34df24241549ad420d7b3948294
    50 Ncb533bd29b6b458aaed51eeb241571d5
    51 sg:journal.1022309
    52 schema:name Influence of geometric and electronic features of pyridine derivatives and triethylamine on the formation of a metal carboxylate core in reactions producing cadmium(ii) pivalate complexes
    53 schema:pagination 1198-1207
    54 schema:productId N9629f8162d1e4609a21aff0b8e7453ea
    55 Na75ad2f6f211413ba002659b7dd9fa5c
    56 Nf7372761ffde4bac96cb896b13dd34d1
    57 schema:sameAs https://app.dimensions.ai/details/publication/pub.1074214306
    58 https://doi.org/10.1007/s11172-016-1436-6
    59 schema:sdDatePublished 2019-04-11T10:21
    60 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    61 schema:sdPublisher N17c9286dcb524f8d8bbf82c5e4f7fe19
    62 schema:url https://link.springer.com/10.1007%2Fs11172-016-1436-6
    63 sgo:license sg:explorer/license/
    64 sgo:sdDataset articles
    65 rdf:type schema:ScholarlyArticle
    66 N17c9286dcb524f8d8bbf82c5e4f7fe19 schema:name Springer Nature - SN SciGraph project
    67 rdf:type schema:Organization
    68 N2d86c34df24241549ad420d7b3948294 schema:volumeNumber 65
    69 rdf:type schema:PublicationVolume
    70 N412345c8ffe34daca7a19b729ea45639 rdf:first sg:person.016256220664.16
    71 rdf:rest Nfc62e6b867b64aa99a4cfc2a94f39c64
    72 N6d7938875a624a2d94e57f85ab9d3190 rdf:first sg:person.012055671403.47
    73 rdf:rest N91902a28a20f4303acc6a60dc164acf1
    74 N87dcd2f34eb14b678fedb43c3a1b8854 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
    75 schema:familyName Gogoleva
    76 schema:givenName N. V.
    77 rdf:type schema:Person
    78 N91902a28a20f4303acc6a60dc164acf1 rdf:first sg:person.01172445335.81
    79 rdf:rest N412345c8ffe34daca7a19b729ea45639
    80 N9629f8162d1e4609a21aff0b8e7453ea schema:name readcube_id
    81 schema:value e319ab50f3b350c405d1dcc69aed0c375ea73509a233d7c75cb96f46a4635268
    82 rdf:type schema:PropertyValue
    83 Na75ad2f6f211413ba002659b7dd9fa5c schema:name dimensions_id
    84 schema:value pub.1074214306
    85 rdf:type schema:PropertyValue
    86 Nc802dea463a3492b961411e64e6942ca rdf:first N87dcd2f34eb14b678fedb43c3a1b8854
    87 rdf:rest N6d7938875a624a2d94e57f85ab9d3190
    88 Ncb533bd29b6b458aaed51eeb241571d5 schema:issueNumber 5
    89 rdf:type schema:PublicationIssue
    90 Nf7372761ffde4bac96cb896b13dd34d1 schema:name doi
    91 schema:value 10.1007/s11172-016-1436-6
    92 rdf:type schema:PropertyValue
    93 Nf9c1fe254dd9430f9fe5bd476c19f902 rdf:first sg:person.0745631435.08
    94 rdf:rest rdf:nil
    95 Nfc62e6b867b64aa99a4cfc2a94f39c64 rdf:first sg:person.014044746763.06
    96 rdf:rest Nf9c1fe254dd9430f9fe5bd476c19f902
    97 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    98 schema:name Chemical Sciences
    99 rdf:type schema:DefinedTerm
    100 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
    101 schema:name Inorganic Chemistry
    102 rdf:type schema:DefinedTerm
    103 sg:journal.1022309 schema:issn 1066-5285
    104 1573-9171
    105 schema:name Russian Chemical Bulletin
    106 rdf:type schema:Periodical
    107 sg:person.01172445335.81 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
    108 schema:familyName Kiskin
    109 schema:givenName M. A.
    110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81
    111 rdf:type schema:Person
    112 sg:person.012055671403.47 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
    113 schema:familyName Shmelev
    114 schema:givenName M. A.
    115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012055671403.47
    116 rdf:type schema:Person
    117 sg:person.014044746763.06 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
    118 schema:familyName Sidorov
    119 schema:givenName A. A.
    120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014044746763.06
    121 rdf:type schema:Person
    122 sg:person.016256220664.16 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
    123 schema:familyName Aleksandrov
    124 schema:givenName G. G.
    125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016256220664.16
    126 rdf:type schema:Person
    127 sg:person.0745631435.08 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
    128 schema:familyName Eremenko
    129 schema:givenName I. L.
    130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08
    131 rdf:type schema:Person
    132 sg:pub.10.1007/978-3-662-04201-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013278232
    133 https://doi.org/10.1007/978-3-662-04201-4
    134 rdf:type schema:CreativeWork
    135 sg:pub.10.1007/bf02494824 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010704813
    136 https://doi.org/10.1007/bf02494824
    137 rdf:type schema:CreativeWork
    138 sg:pub.10.1007/bf02494929 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015160210
    139 https://doi.org/10.1007/bf02494929
    140 rdf:type schema:CreativeWork
    141 sg:pub.10.1007/bf02496153 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005547948
    142 https://doi.org/10.1007/bf02496153
    143 rdf:type schema:CreativeWork
    144 sg:pub.10.1007/s10876-005-0009-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1032770944
    145 https://doi.org/10.1007/s10876-005-0009-x
    146 rdf:type schema:CreativeWork
    147 sg:pub.10.1007/s11172-006-0212-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020586896
    148 https://doi.org/10.1007/s11172-006-0212-4
    149 rdf:type schema:CreativeWork
    150 sg:pub.10.1007/s11172-007-0267-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1037839699
    151 https://doi.org/10.1007/s11172-007-0267-x
    152 rdf:type schema:CreativeWork
    153 sg:pub.10.1007/s11172-010-0220-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018561253
    154 https://doi.org/10.1007/s11172-010-0220-2
    155 rdf:type schema:CreativeWork
    156 sg:pub.10.1023/a:1011349727749 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046970222
    157 https://doi.org/10.1023/a:1011349727749
    158 rdf:type schema:CreativeWork
    159 sg:pub.10.1023/b:rucb.0000011866.57209.5b schema:sameAs https://app.dimensions.ai/details/publication/pub.1043976446
    160 https://doi.org/10.1023/b:rucb.0000011866.57209.5b
    161 rdf:type schema:CreativeWork
    162 sg:pub.10.1023/b:rucb.0000024860.24003.61 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041713573
    163 https://doi.org/10.1023/b:rucb.0000024860.24003.61
    164 rdf:type schema:CreativeWork
    165 sg:pub.10.1134/s0036023606080110 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023636565
    166 https://doi.org/10.1134/s0036023606080110
    167 rdf:type schema:CreativeWork
    168 sg:pub.10.1134/s0036023606100135 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051892493
    169 https://doi.org/10.1134/s0036023606100135
    170 rdf:type schema:CreativeWork
    171 https://app.dimensions.ai/details/publication/pub.1013278232 schema:CreativeWork
    172 https://doi.org/10.1002/ejic.200900821 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049080861
    173 rdf:type schema:CreativeWork
    174 https://doi.org/10.1016/j.ica.2009.06.035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035308128
    175 rdf:type schema:CreativeWork
    176 https://doi.org/10.1016/j.ica.2011.01.040 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050787284
    177 rdf:type schema:CreativeWork
    178 https://doi.org/10.1016/j.ica.2011.10.056 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000919836
    179 rdf:type schema:CreativeWork
    180 https://doi.org/10.1016/j.ica.2012.03.031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003616173
    181 rdf:type schema:CreativeWork
    182 https://doi.org/10.1016/j.inoche.2004.11.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049779436
    183 rdf:type schema:CreativeWork
    184 https://doi.org/10.1016/j.jinorgbio.2014.06.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029203820
    185 rdf:type schema:CreativeWork
    186 https://doi.org/10.1016/j.mencom.2011.04.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033008721
    187 rdf:type schema:CreativeWork
    188 https://doi.org/10.1016/j.molstruc.2006.12.013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039172418
    189 rdf:type schema:CreativeWork
    190 https://doi.org/10.1016/j.molstruc.2014.03.052 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035939028
    191 rdf:type schema:CreativeWork
    192 https://doi.org/10.1016/j.molstruc.2014.07.067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051247827
    193 rdf:type schema:CreativeWork
    194 https://doi.org/10.1016/j.poly.2006.10.010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024331324
    195 rdf:type schema:CreativeWork
    196 https://doi.org/10.1016/j.poly.2008.09.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050149088
    197 rdf:type schema:CreativeWork
    198 https://doi.org/10.1016/j.poly.2014.03.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035423688
    199 rdf:type schema:CreativeWork
    200 https://doi.org/10.1021/ic00175a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055545971
    201 rdf:type schema:CreativeWork
    202 https://doi.org/10.1021/ic050475x schema:sameAs https://app.dimensions.ai/details/publication/pub.1055557865
    203 rdf:type schema:CreativeWork
    204 https://doi.org/10.1021/ic0522028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055558894
    205 rdf:type schema:CreativeWork
    206 https://doi.org/10.1021/ic981292w schema:sameAs https://app.dimensions.ai/details/publication/pub.1055589338
    207 rdf:type schema:CreativeWork
    208 https://doi.org/10.1021/ja00007a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055698479
    209 rdf:type schema:CreativeWork
    210 https://doi.org/10.1021/ja9831094 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055870751
    211 rdf:type schema:CreativeWork
    212 https://doi.org/10.1039/b711650k schema:sameAs https://app.dimensions.ai/details/publication/pub.1022812376
    213 rdf:type schema:CreativeWork
    214 https://doi.org/10.1039/dt9950001519 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029255995
    215 rdf:type schema:CreativeWork
    216 https://doi.org/10.1107/s0108270192005808 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016420631
    217 rdf:type schema:CreativeWork
    218 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
    219 rdf:type schema:CreativeWork
    220 https://doi.org/10.1107/s1600536808005102 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022365836
    221 rdf:type schema:CreativeWork
    222 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
    223 schema:name N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation
    224 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...