2D coordination polymers of AgI—MII (MII = Ni, Cu) with anions of substituted malonic acids View Full Text


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Article Info

DATE

2016-03

AUTHORS

E. N. Zorina-Tikhonova, N. V. Gogoleva, E. V. Aleksandrov, G. G. Aleksandrov, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko

ABSTRACT

Heterometallic malonate complexes [Ag2Ni(H2O)2(R2mal)2]n (R2mal2– is the dimethylmalonate dianion (Me2mal2–) (1) or the cyclobutane-1,1-dicarboxylate dianion (Cbdc2–) (2)) and [Ag2Cu(H2O)(Me2mal)2]n (3) were synthesized. The bis-chelate fragment {M(R2mal)2} (M = Ni, Cu) composed of two dianions of an acid and a 3d metal atom is the structure-forming unit of these complexes. The mononuclear fragments are linked by silver(I) atoms, which are involved in argentophilic interactions, to form 2D coordination polymers. More... »

PAGES

759-766

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-016-1370-7

DOI

http://dx.doi.org/10.1007/s11172-016-1370-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038267169


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