Reactions of 3,5-di-tert-butyl-1,2-benzoquinone with mercapto carboxylic acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-03

AUTHORS

L. Yu. Ukhin, K. Yu. Suponitsky, E. N. Shepelenko, L. V. Belousova, D. V. Alekseenko, G. S. Borodkin, L. N. Etmetchenko

ABSTRACT

Heating of an equimolar mixture of 3,5-di-tert-butyl-1,2-benzoquinone with thiosalicylic acid led to 2-[(4,6-di-tert-butyl-2,3-dihydroxyphenyl)thio]benzoic acid. In the case of β-mercaptopropionic acid, 2-[(4,6-di-tert-butyl-2,3-dihydroxyphenyl)thio]propionic acid was formed, which upon reflux in Ac2O was converted to 6,8-di-tert-butyl-9-hydroxy-3,4-dihydro-2H-1,5benzoxathiepin-2-one.

PAGES

727-730

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-016-1363-6

DOI

http://dx.doi.org/10.1007/s11172-016-1363-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036526048


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