Ontology type: schema:ScholarlyArticle
2015-12
AUTHORSA. K. Shiryaev, R. S. Belen´kaya, V. A. Shiryaev, V. B. Rybakov, Yu. N. Klimochkin
ABSTRACTMethyl adamantane-1-carboxylate and methyl (1-adamantyl)acetate react with acetonitrile in the presence of sodium hydride to give 3-(1-adamantyl)-3-oxopropanenitrile and 4-(1-adamantyl)-3-oxobutanenitrile, respectively. Reaction involving methyl (1-adamantyl)-acetate produces also 2-(1-adamantyl)-N-(E-1-cyanoprop-1-ene-2-yl)acetamide; the structure of this side product was established by X-ray diffraction analysis.
PAGES2966-2969
http://scigraph.springernature.com/pub.10.1007/s11172-015-1256-0
DOIhttp://dx.doi.org/10.1007/s11172-015-1256-0
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