Reactions of methyl esters of adamantane acids with acetonitrile View Full Text


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Article Info

DATE

2015-12

AUTHORS

A. K. Shiryaev, R. S. Belen´kaya, V. A. Shiryaev, V. B. Rybakov, Yu. N. Klimochkin

ABSTRACT

Methyl adamantane-1-carboxylate and methyl (1-adamantyl)acetate react with acetonitrile in the presence of sodium hydride to give 3-(1-adamantyl)-3-oxopropanenitrile and 4-(1-adamantyl)-3-oxobutanenitrile, respectively. Reaction involving methyl (1-adamantyl)-acetate produces also 2-(1-adamantyl)-N-(E-1-cyanoprop-1-ene-2-yl)acetamide; the structure of this side product was established by X-ray diffraction analysis.

PAGES

2966-2969

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-015-1256-0

DOI

http://dx.doi.org/10.1007/s11172-015-1256-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028617874


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