Synthesis, crystal structure, and luminescence properties of complexes (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-11

AUTHORS

Yu. A. Vorotnikov, M. A. Mikhailov, K. A. Brylev, D. A. Piryazev, N. V. Kuratieva, M. N. Sokolov, Yu. V. Mironov, M. A. Shestopalov

ABSTRACT

Two new compounds based on octahedral molybdenum and tungsten iodide cluster complexes of the composition (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium) were synthesized and structurally characterized. The luminescence properties of powder samples of the synthesized compounds and of the salts (Bu4N)2[{M6(µ3-I)8}I6] described earlier were investigated. Due to the presence of the vinylcontaining cation, these compounds can be involved in radical copolymerization in order to produce polymeric luminescent materials. More... »

PAGES

2591-2596

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-015-1194-x

DOI

http://dx.doi.org/10.1007/s11172-015-1194-x

DIMENSIONS

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