Selective deoxygenation of vegetable oils in the presence of Pt–Sn/Al2O3 catalyst View Full Text


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Article Info

DATE

2015-09

AUTHORS

M. V. Tsodikov, A. V. Chistyakov, M. A. Gubanov, P. A. Zharova, S. S. Shapovalov, A. A. Pasynskii, V. V. Kriventsov, I. I. Moiseev

ABSTRACT

We studied deoxygenation of individual fatty esters and fatty acid triglycerides from vegetable oils and lipid extracts from microalgae in the presence of catalysts prepared by deposition of Pt–Sn-containing compounds onto the γ-aluminum oxide surface. Using individual esters as an example, selective reduction of oxygen into water was demonstrated for the first time to proceed on a catalytic system at the 5 : 1 molar ratio of Sn and Pt active components to afford hydrocarbon components of substrates in virtually quantitative yield. Transformation of vegetable oil in the presence of this catalyst affords the C3–C18 hydrocarbon fraction in yield up to 99% at the content of C3 and C18 hydrocarbons up to 90%. The fraction of C1 and C2 hydrocarbons and carbon oxides is not higher than 0.5%. The possibility of carbon weight loss minimization during transformation of lipids was shown for the first time. More... »

PAGES

2062-2068

References to SciGraph publications

  • 1977-12. Каталитические свойства системы (Pt−Sn)/Al2O3 in REACTION KINETICS AND CATALYSIS LETTERS
  • 2014-03. Stannylene complexes of manganese, iron, and platinum in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • 2012-12. Direct highly selective conversion of fatty acid triglycerides to fuel components in DOKLADY CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-015-1118-9

    DOI

    http://dx.doi.org/10.1007/s11172-015-1118-9

    DIMENSIONS

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