Thermal decomposition of [Co(NH3)6][Fe(C2O4)3]•3H2O in inert and reductive atmospheres View Full Text


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Article Info

DATE

2015-08

AUTHORS

Yu. P. Semushina, P. E. Plyusnin, Yu. V. Shubin, S. I. Pechenyuk, Yu. V. Ivanov

ABSTRACT

The thermal decomposition of [Co(NH3)6][Fe(C2O4)3]•3H2O in hydrogen and helium atmospheres was studied. The thermal decomposition of the complex proceeds via the same four steps in a temperature range of 50—430 °C, regardless of the atmosphere. The thermolysis processes in inert and reductive atmospheres differ by the nature of the final solid products: a Co0.5Fe0.5 alloys is formed in a hydrogen atmosphere, and a mixture of iron and cobalt oxides is observed for an inert atmosphere. The major gaseous decomposition products are H2O, NH3, CO2, and CO. More... »

PAGES

1963-1966

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-015-1100-6

DOI

http://dx.doi.org/10.1007/s11172-015-1100-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039726528


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