Nitration of 1,3,3-trimethyl-1-phenylindane on mesoporous aluminosilicates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-04

AUTHORS

N. G. Grigorieva, M. R. Agliullin, V. P. Talzi, O. V. Vodyankina, B. I. Kutepov

ABSTRACT

Nitration of 1,3,3-trimethyl-1-phenylindane (phenylindane) by nitric acid of different concentration over mesoporous aluminosilicates with the molar ratios SiO2 : Al2O3 = 20, 40, and 80 was studied. The effects of the SiO2 : Al2O3 and phenylindane : nitric acid ratios, the concentration of nitric acid, and temperature on the conversion of phenylindane and the yield of dinitrophenylindane were revealed. The aluminosilicate samples with a SiO2 : Al2O3 ratio of 20 are shown to have the highest activity. In the presence of these samples, the conversion of phenylindane reaches 100% with a selectivity of formation of 5and 6-nitro-1-(4´-nitrophenyl)1,3,3-trimethylindanes close to 80% (70% nitric acid, 100 °C). More... »

PAGES

852-858

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-015-0944-0

DOI

http://dx.doi.org/10.1007/s11172-015-0944-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025891700


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