Cobalt(II) complexes with bis-2,4-[N-(S)-phenylalanyl]-6-chlorotriazine: synthesis, structure, and application for separation of enantiomers of butan-2-ol View Full Text


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Article Info

DATE

2015-03

AUTHORS

Yu. A. Satskaya, N. P. Komarova, K. S. Gavrilenko, O. V. Manoylenko, M. A. Kiskin, S. V. Kolotilov, I. L. Eremenko, V. M. Novotortsev

ABSTRACT

The chiral coordination compounds [Co(L)(H2O)2(MeOH)]n (1) and Co2(L)2(H2O)(MeOH)4 (2) were synthesized by the reaction of bis-2,4-[N-(S)-phenylalanyl]6-chlorotriazine (LH2) with cobalt(II) pivalate or acetate. In molecules 2, the CoII ions are linked by a bridging water molecule and two carboxy groups of the L2– anion. By passing the racemate of butan-2-ol through a chromatographic column containing complex 1 as the stationary phase, a mixture enriched with the (S)-isomer of this alcohol can be obtained. More... »

PAGES

630-635

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-015-0910-x

DOI

http://dx.doi.org/10.1007/s11172-015-0910-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011547609


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