Synthesis of a tetranuclear mixed-ligand CoII complex with pivalate and acetate View Full Text


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Article Info

DATE

2015-03

AUTHORS

E. Yu. Fursova, G. V. Romanenko, R. Z. Sagdeev, V. I. Ovcharenko

ABSTRACT

When studying the synthesis of NBu4[Co(piv)3] and NBu4[Cu(piv)3], where NBu4 is a tetrabutylammonium cation and piv is a pivalate anion, in some cases we obtained a few crystals of the tetranuclear complexes (NBu4)2[M4(piv)8(AcO)2(H2O)n], where M = Co, n = 4; M = Cu, n = 2, AcO is the acetate anion. These complexes contain only deprotonated pivalate and acetate anions as coordinated organic ligands and represent a rare type of polynuclear compounds, which have not been obtained earlier as the major individual phase. For CoII, a method was developed for the straightforward synthesis of the complex (NBu4)2[Co4(piv)8(AcO)2(H2O)4]. More... »

PAGES

626-629

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-015-0909-3

DOI

http://dx.doi.org/10.1007/s11172-015-0909-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016879919


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