Synthesis of a tetranuclear mixed-ligand CoII complex with pivalate and acetate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-03

AUTHORS

E. Yu. Fursova, G. V. Romanenko, R. Z. Sagdeev, V. I. Ovcharenko

ABSTRACT

When studying the synthesis of NBu4[Co(piv)3] and NBu4[Cu(piv)3], where NBu4 is a tetrabutylammonium cation and piv is a pivalate anion, in some cases we obtained a few crystals of the tetranuclear complexes (NBu4)2[M4(piv)8(AcO)2(H2O)n], where M = Co, n = 4; M = Cu, n = 2, AcO is the acetate anion. These complexes contain only deprotonated pivalate and acetate anions as coordinated organic ligands and represent a rare type of polynuclear compounds, which have not been obtained earlier as the major individual phase. For CoII, a method was developed for the straightforward synthesis of the complex (NBu4)2[Co4(piv)8(AcO)2(H2O)4]. More... »

PAGES

626-629

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-015-0909-3

DOI

http://dx.doi.org/10.1007/s11172-015-0909-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016879919


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fursova", 
        "givenName": "E. Yu.", 
        "id": "sg:person.07501453217.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Romanenko", 
        "givenName": "G. V.", 
        "id": "sg:person.0664032236.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sagdeev", 
        "givenName": "R. Z.", 
        "id": "sg:person.0771743570.83", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771743570.83"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ovcharenko", 
        "givenName": "V. I.", 
        "id": "sg:person.0732145436.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2015-03", 
    "datePublishedReg": "2015-03-01", 
    "description": "When studying the synthesis of NBu4[Co(piv)3] and NBu4[Cu(piv)3], where NBu4 is a tetrabutylammonium cation and piv is a pivalate anion, in some cases we obtained a few crystals of the tetranuclear complexes (NBu4)2[M4(piv)8(AcO)2(H2O)n], where M = Co, n = 4; M = Cu, n = 2, AcO is the acetate anion. These complexes contain only deprotonated pivalate and acetate anions as coordinated organic ligands and represent a rare type of polynuclear compounds, which have not been obtained earlier as the major individual phase. For CoII, a method was developed for the straightforward synthesis of the complex (NBu4)2[Co4(piv)8(AcO)2(H2O)4].", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s11172-015-0909-3", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1063-5211", 
          "1026-3500"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "64"
      }
    ], 
    "keywords": [
      "acetate anions", 
      "polynuclear compounds", 
      "organic ligands", 
      "pivalate anion", 
      "tetrabutylammonium cation", 
      "tetranuclear complexes", 
      "straightforward synthesis", 
      "anions", 
      "CoII", 
      "synthesis", 
      "complexes", 
      "pivalate", 
      "NBu4", 
      "cations", 
      "ligands", 
      "compounds", 
      "CO", 
      "individual phases", 
      "crystals", 
      "Cu", 
      "phase", 
      "method", 
      "ACO", 
      "types", 
      "cases", 
      "PIV", 
      "rare type", 
      "major individual phase", 
      "tetranuclear mixed-ligand CoII", 
      "mixed-ligand CoII"
    ], 
    "name": "Synthesis of a tetranuclear mixed-ligand CoII complex with pivalate and acetate", 
    "pagination": "626-629", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1016879919"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-015-0909-3"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-015-0909-3", 
      "https://app.dimensions.ai/details/publication/pub.1016879919"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:36", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_663.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s11172-015-0909-3"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-015-0909-3'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-015-0909-3'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-015-0909-3'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-015-0909-3'


 

This table displays all metadata directly associated to this object as RDF triples.

109 TRIPLES      21 PREDICATES      56 URIs      48 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-015-0909-3 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Nca409c4065fb47ca8a2fbf37246223c3
4 schema:datePublished 2015-03
5 schema:datePublishedReg 2015-03-01
6 schema:description When studying the synthesis of NBu4[Co(piv)3] and NBu4[Cu(piv)3], where NBu4 is a tetrabutylammonium cation and piv is a pivalate anion, in some cases we obtained a few crystals of the tetranuclear complexes (NBu4)2[M4(piv)8(AcO)2(H2O)n], where M = Co, n = 4; M = Cu, n = 2, AcO is the acetate anion. These complexes contain only deprotonated pivalate and acetate anions as coordinated organic ligands and represent a rare type of polynuclear compounds, which have not been obtained earlier as the major individual phase. For CoII, a method was developed for the straightforward synthesis of the complex (NBu4)2[Co4(piv)8(AcO)2(H2O)4].
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N4cebe6a8ebdc4cb2a819b24eb4e86225
11 N8851cd6e2aaa4216837cdf5c5d760227
12 sg:journal.1022309
13 schema:keywords ACO
14 CO
15 CoII
16 Cu
17 NBu4
18 PIV
19 acetate anions
20 anions
21 cases
22 cations
23 complexes
24 compounds
25 crystals
26 individual phases
27 ligands
28 major individual phase
29 method
30 mixed-ligand CoII
31 organic ligands
32 phase
33 pivalate
34 pivalate anion
35 polynuclear compounds
36 rare type
37 straightforward synthesis
38 synthesis
39 tetrabutylammonium cation
40 tetranuclear complexes
41 tetranuclear mixed-ligand CoII
42 types
43 schema:name Synthesis of a tetranuclear mixed-ligand CoII complex with pivalate and acetate
44 schema:pagination 626-629
45 schema:productId Nc1c9d7d505634d74b06045b1dd8cff0c
46 Ne4050f060e89440da95f0d9ac7f72c3d
47 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016879919
48 https://doi.org/10.1007/s11172-015-0909-3
49 schema:sdDatePublished 2022-01-01T18:36
50 schema:sdLicense https://scigraph.springernature.com/explorer/license/
51 schema:sdPublisher Nb5a42a7cd3f14625823cf22ac53574e0
52 schema:url https://doi.org/10.1007/s11172-015-0909-3
53 sgo:license sg:explorer/license/
54 sgo:sdDataset articles
55 rdf:type schema:ScholarlyArticle
56 N2ab4b6f796634532bb58d26717cd8180 rdf:first sg:person.0664032236.40
57 rdf:rest N4a8aef8302bc4730a3b3a337d113518b
58 N4a8aef8302bc4730a3b3a337d113518b rdf:first sg:person.0771743570.83
59 rdf:rest Ncf7db139dcd44f58a3be9009b7e97e78
60 N4cebe6a8ebdc4cb2a819b24eb4e86225 schema:volumeNumber 64
61 rdf:type schema:PublicationVolume
62 N8851cd6e2aaa4216837cdf5c5d760227 schema:issueNumber 3
63 rdf:type schema:PublicationIssue
64 Nb5a42a7cd3f14625823cf22ac53574e0 schema:name Springer Nature - SN SciGraph project
65 rdf:type schema:Organization
66 Nc1c9d7d505634d74b06045b1dd8cff0c schema:name dimensions_id
67 schema:value pub.1016879919
68 rdf:type schema:PropertyValue
69 Nca409c4065fb47ca8a2fbf37246223c3 rdf:first sg:person.07501453217.49
70 rdf:rest N2ab4b6f796634532bb58d26717cd8180
71 Ncf7db139dcd44f58a3be9009b7e97e78 rdf:first sg:person.0732145436.56
72 rdf:rest rdf:nil
73 Ne4050f060e89440da95f0d9ac7f72c3d schema:name doi
74 schema:value 10.1007/s11172-015-0909-3
75 rdf:type schema:PropertyValue
76 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
77 schema:name Chemical Sciences
78 rdf:type schema:DefinedTerm
79 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
80 schema:name Organic Chemistry
81 rdf:type schema:DefinedTerm
82 sg:journal.1022309 schema:issn 1026-3500
83 1063-5211
84 schema:name Russian Chemical Bulletin
85 schema:publisher Springer Nature
86 rdf:type schema:Periodical
87 sg:person.0664032236.40 schema:affiliation grid-institutes:grid.415877.8
88 schema:familyName Romanenko
89 schema:givenName G. V.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40
91 rdf:type schema:Person
92 sg:person.0732145436.56 schema:affiliation grid-institutes:grid.415877.8
93 schema:familyName Ovcharenko
94 schema:givenName V. I.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56
96 rdf:type schema:Person
97 sg:person.07501453217.49 schema:affiliation grid-institutes:grid.415877.8
98 schema:familyName Fursova
99 schema:givenName E. Yu.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49
101 rdf:type schema:Person
102 sg:person.0771743570.83 schema:affiliation grid-institutes:grid.415877.8
103 schema:familyName Sagdeev
104 schema:givenName R. Z.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771743570.83
106 rdf:type schema:Person
107 grid-institutes:grid.415877.8 schema:alternateName International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation
108 schema:name International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation
109 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...