Novel catalysts for selective hydrogenation of C≡C bond based on Pd nanoparticles immobilized in phenylenecarboxylate frameworks (NH2)-MIL-53(Al) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-02

AUTHORS

A. Yu. Stakheev, V. I. Isaeva, P. V. Markov, O. V. Turova, I. S. Mashkovskii, G. I. Kapustin, B. R. Saifutdinov, L. M. Kustov

ABSTRACT

Novel catalysts based on Pd nanoparticles encapsulated into microporous metal-organic framework MIL-53(Al) and NH2-MIL-53(Al) were synthesized. Their catalytic properties were studied in the model reaction of liquid-phase hydrogenation of diphenylacetylene (DPA) (293 K, \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$P_{H_2 }$$\end{document} = 5 atm). The activity and selectively of the palladium-containing materials Pd—MIL in DPA hydrogenation depend substantially on the nature of the organic linker. More... »

PAGES

284-290

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-015-0858-x

DOI

http://dx.doi.org/10.1007/s11172-015-0858-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1045666415


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