Reactions of 1,1-difluoroalkylzinc halides with chlorinating reagents View Full Text


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Article Info

DATE

2014-11

AUTHORS

V. O. Smirnov, A. S. Maslov, V. V. Levin, M. I. Struchkova, A. D. Dilman

ABSTRACT

Compounds bearing chlorodifluoromethyl group can be assembled from organozinc chlorides, (chlorodifluoromethyl)trimethylsilane (Me3SiCF2Cl), and sulfuryl chloride as a chlorine source. Reactions of 1,1-difluoro-substituted organozinc bromides (RCF2ZnBr) with different chlorinating reagents lead to predominant or partial formation of the products bearing bromodifluoromethyl group.

PAGES

2564-2566

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-014-0778-1

DOI

http://dx.doi.org/10.1007/s11172-014-0778-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002589765


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