Ethyl 5-ferrocenyl-1H-pyrazolecarboxylates: The synthesis and redox properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-10

AUTHORS

V. N. Kulikov, O. M. Nikitin, Yu. A. Borisov, A. S. Makarov, A. N. Rodionov, R. S. Nikulin, L. V. Kovalenko, Yu. A. Belousov

ABSTRACT

Redox potentials of isomeric ethyl 5-ferrocenyl-1H-pyrazole-3-carboxylates 2 and ethyl 5-ferrocenyl-1H-pyrazole-4-carboxylates 4 were measured and their dependences on the acidity of the medium were determined. The structures of various conformers of neutral molecules and corresponding radical cations were calculated by the B3LYP/6-31G* method. The results of calculations for neutral molecules were confirmed by X-ray data. More... »

PAGES

2255-2259

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-014-0731-3

DOI

http://dx.doi.org/10.1007/s11172-014-0731-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048234062


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