Adducts of lanthanide acetylacetonates with 5-phenyl-2-(2-pyridyl)-7,8-benzo-6,5-dihydro-1,3,6-triazaindolizine: structure and photoluminescence View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

A. N. Gusev, V. F. Shul’gin, W. Linert, M. Hasegawa, G. G. Aleksandrov, I. L. Eremenko

ABSTRACT

A series of isostructural complexes of the formula Ln(acac)3L (where Hacac is the acetylacetone, L is the 5-phenyl-2-(2-pyridyl)-7,8-benzo-6,5-dihydro-1,3,6-triazaindolizine, Ln are the LaIII, TbIII, EuIII, and SmIII) was studied. Molecular and crystal structures of terbium and samarium complexes were established by X-ray diffraction analysis. Luminescence properties of solid samples were studied. Coordination of 5-phenyl-2-(2-pyridyl)-7,8-benzo-6,5-dihydro-1,3,6-triazaindolizine as an additional ligand increases intensity of photoluminescence. Luminescence spectra of compositions EuxTb1−x(acac)3L and La0.6Eu0.1Tb0.3(acac)3L were studied. A combination of several lanthanide ions allowed us to obtain almost white emission. More... »

PAGES

1493-1497

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-014-0625-4

DOI

http://dx.doi.org/10.1007/s11172-014-0625-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025147592


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