Thiacalix[4]arene-containing M2Ln2 complexes (M = MnII, CoII; Ln = EuIII, PrIII): synthesis, structure, and magnetic properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

S. M. Aldoshin, N. A. Sanina, S. E. Solov’eva, I. S. Antipin, A. I. Dmitriev, R. B. Morgunov, D. V. Korchagin, G. V. Shilov, A. N. Utenyshev, K. V. Bozhenko

ABSTRACT

Three new representatives of thiacalix[4]arene-containing tetranuclear 3d-4f metal complexes with the M2Ln2 fragment (M = MnII, CoII; Ln = EuIII, PrIII) were synthesized. Their molecular and crystal structures were studied by X-ray diffraction analysis. According to the magnetochemical measurements, the complexes exhibit the paramagnetic properties with weak antiferromagnetic interactions at low temperatures (T < 30–50 K). The influence of the environment of the rare-earth elements on the spin-orbital coupling and magnetic properties of the complexes was found. More... »

PAGES

1465-1474

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-014-0622-7

DOI

http://dx.doi.org/10.1007/s11172-014-0622-7

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https://app.dimensions.ai/details/publication/pub.1024156731


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