Complexes of lanthanides with spin-labeled pyrazolylquinoline View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

E. V. Tretyakov, S. V. Fokin, E. M. Zueva, A. O. Tkacheva, G. V. Romanenko, A. S. Bogomyakov, S. V. Larionov, S. A. Popov, V. I. Ovcharenko

ABSTRACT

The reactions of EuIII, GdIII, and TbIII hexafluoroacetylacetonates with 4,4,5,5-tetramethyl-2-[1-(4-methylquinolin-2-yl)-1H-pyrazol-4-yl]-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (L) afford heterospin complexes [Ln(hfac)3L2]. The X-ray diffraction studies of the complexes showed that the ligand L is coordinated in a monodentate fashion through the oxygen atom of the >N-O group. According to the magnetochemical data, at temperatures below 3 K the complex [Tb(hfac)3L2] exhibits properties of a single-molecule magnet with an anisotropy barrier of 12.2 cm−1. More... »

PAGES

1459-1464

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-014-0621-8

DOI

http://dx.doi.org/10.1007/s11172-014-0621-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020086098


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