Ontology type: schema:ScholarlyArticle
2014-06
AUTHORSN. V. Gogoleva, E. N. Zorina-Tikhonova, N. N. Efimov, E. A. Ugolkova, A. S. Bogomyakov, S. V. Kolotilov, M. A. Kiskin, G. G. Aleksandrov, V. V. Minin, A. A. Sidorov, V. M. Novotortsev, I. L. Eremenko
ABSTRACTThe reactions of transition metal trimethylacetates [Cu2(Piv)4(HPiv)2], [Ni9(OH)6(Piv)12(HPiv)4], [Co(Piv)2]n (Piv− = −O2CBut) with 1,1-cyclohexanediacetic acid (H2Chda) neutralized by tetrabutylammonium hydroxide in the presence of 2,2-bipyridine (2,2′-bpy) afford linear trinuclear homometallic complexes [(2,2′-bpy)2Cu3(Chda)2(Piv)2]··2EtOH (1) and [(2,2′-bpy)2M3(Chda)2(Piv)2(EtOH)2] (M = NiII (2) or CoII (3)). In molecules of these compounds, anions of both mono- and dicarboxylic acids act as bridges between the transition metal atoms. Compounds 1–3 were characterized by X-ray diffraction, and their magnetic properties were studied. Spin-spin ferromagnetic interactions dominate in complexes 1–3 with CuII (S = 1/2) (1) and CoII (S = 3/2) (3) ions. More... »
PAGES1301-1307
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DOIhttp://dx.doi.org/10.1007/s11172-014-0594-7
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